The phenomenon of single-molecule magnetism was established in the early 1990s with the
cluster [Mn 12 O 12 (AcO) 16 (H 2 O) 4]. Since then, a large number of compounds …

Polynuclear coordination clusters have become of particular interest in recent times as a
result of their relevance to bioinorganic chemistry and to the special area of molecule-based …

Two-electron oxidation of [{Pc (OEt) 8} 2TbIII]-[Pc (OEt) 8= dianion of 2, 3, 9, 10, 16, 17, 23,
24-octaethoxyphthalocyanine], which leads to a longitudinal contraction of the coordination …

The reaction between oxide-centered, triangular [MnIII3O (O2CR) 6 (py) 3](ClO4)(R= Me (1),
Et (2), Ph (3)) compounds and methyl 2-pyridyl ketone oxime (mpkoH) affords a new family …

This review covers single-molecule magnets, not only focussing on developments since
2005 but also including coverage of earlier work where necessary for understanding of …

Electrospray (ESI) and cryospray mass spectrometry (CSI-MS) are proving to be
exceptionally versatile tools when used in conjunction with high resolution time-of-flight …

Detailed studies are reported of a Mn12 single-molecule magnet (SMM) in truly axial
(tetragonal) symmetry. The complex is [Mn12O12 (O2CCH2Br) 16 (H2O) 4]⊙ 4CH2Cl2 (2⊙ …

Using tripodal alcohols to build high-spin molecules and single-molecule magnets - Chemical
Communications (RSC Publishing) DOI:10.1039/B510102F Royal Society of Chemistry View …

Reaction of copper powder with Mn (OAc) 2⊙ 4H2O and triethanolamine in DMF solution in
air yields a high nuclearity, mixed-valent CuI4CuII13MnII4MnIII12MnIV12 cluster. X-ray …

Single-molecule magnets (SMMs) are a class of coordination compounds that attract
attention because of their magnetic bistability.[1] These finite-size molecules show a slow …