[HTML][HTML] Reducing the carbon footprint of polyurethanes by chemical and biological depolymerization: Fact or fiction?

LP Fonseca, A Duval, E Luna, M Ximenis… - Current Opinion in …, 2023 - Elsevier
Polyurethanes (PUs) are one of the most widely employed classes of polymers, with a
continuously increasing production demand that is expected to reach around 21 million tons …

Evolution of Copolymers of Epoxides and CO2: Catalysts, Monomers, Architectures, and Applications

GW Yang, R Xie, YY Zhang, CK Xu, GP Wu - Chemical Reviews, 2024 - ACS Publications
The copolymerization of CO2 and epoxides presents a transformative approach to
converting greenhouse gases into aliphatic polycarbonates (CO2-PCs), thereby reducing …

Simultaneous Presence of Open Metal Sites and Amine Groups on a 3D Dy(III)-Metal–Organic Framework Catalyst for Mild and Solvent-Free Conversion of CO2 to …

R Abazari, S Sanati, A Morsali, AM Kirillov… - Inorganic …, 2021 - ACS Publications
Carbon dioxide (CO2) fixation to generate chemicals and fuels is of high current importance,
especially toward finding mild and efficient strategies for catalytic CO2 transformation to …

Scalable, Durable, and Recyclable Metal‐Free Catalysts for Highly Efficient Conversion of CO2 to Cyclic Carbonates

YY Zhang, GW Yang, R Xie, L Yang, B Li… - Angewandte …, 2020 - Wiley Online Library
A series of highly active organoboron catalysts for the coupling of CO2 and epoxides with
the advantages of scalable preparation, thermostability, and recyclability is reported. The …

Deep Eutectic Solvents as Efficient Catalysts for Fixation of CO2 to Cyclic Carbonates at Ambient Temperature and Pressure through Synergetic Catalysis

X Yang, Q Zou, T Zhao, P Chen, Z Liu… - ACS Sustainable …, 2021 - ACS Publications
A series of deep eutectic solvents (DESs), consisting of protic ionic liquids (PILs) and
amines, feature effective catalytic activity for the fixation of CO2 to cyclic carbonates at …

Confined pyrolysis transformation of ZIF-8 to hierarchically ordered porous Zn-NC nanoreactor for efficient CO2 photoconversion under mild conditions

Y Guo, L Feng, C Wu, X Wang, X Zhang - Journal of Catalysis, 2020 - Elsevier
Rational design and fabrication of metal–organic framework (MOF)-derived ordered
hierarchical macro-/meso-/microporous N-doped carbon materials featured with the …

Fully bio-based polyhydroxyurethanes with a dynamic network from a terpene derivative and cyclic carbonate functional soybean oil

X Liu, X Yang, S Wang, S Wang, Z Wang… - ACS Sustainable …, 2021 - ACS Publications
Polyhydroxyurethanes (PHUs), polyurethanes with excellent properties, are cured without
poisonous isocyanate. The carbamate groups in the structure can undergo bond exchange …

Cycloaddition of CO 2 to epoxides “around water”: a strategy to apply and recycle efficient water-soluble bio-based organocatalysts in biphasic media

T Theerathanagorn, A Vidal-López, A Comas-Vives… - Green …, 2023 - pubs.rsc.org
The synthesis of cyclic carbonates by cycloaddition of CO2 to epoxides is a convenient non-
reductive strategy to valorize carbon dioxide. Biphasic chemistry is an emerging and …

Cycloaddition of CO 2 to epoxides by highly nucleophilic 4-aminopyridines: establishing a relationship between carbon basicity and catalytic performance by …

W Natongchai, JA Luque-Urrutia… - Organic Chemistry …, 2021 - pubs.rsc.org
The development of single-component halogen-free organocatalysts in the highly
investigated cycloaddition of CO2 to epoxides is sought-after to enhance the sustainability of …

CO2 conversion into carbonate using pyridinium-based ionic liquids under mild conditions

F Norouzi, A Abdolmaleki - Fuel, 2023 - Elsevier
A sequence of pyridinium-based acidic-ionic liquids (PyAILs) as dual-functional ILs were
synthesized and applied as metal-free, stable and homogeneous catalysts to convert …