Surface coordination chemistry of atomically dispersed metal catalysts

R Qin, K Liu, Q Wu, N Zheng - Chemical Reviews, 2020 - ACS Publications
Atomically dispersed metal catalysts (ADCs), as an emerging class of heterogeneous
catalysts, have been widely investigated during the past two decades. The atomic dispersion …

Metal catalysts for heterogeneous catalysis: from single atoms to nanoclusters and nanoparticles

L Liu, A Corma - Chemical reviews, 2018 - ACS Publications
Metal species with different size (single atoms, nanoclusters, and nanoparticles) show
different catalytic behavior for various heterogeneous catalytic reactions. It has been shown …

Hierarchically porous materials: synthesis strategies and structure design

XY Yang, LH Chen, Y Li, JC Rooke… - Chemical Society …, 2017 - pubs.rsc.org
Owing to their immense potential in energy conversion and storage, catalysis,
photocatalysis, adsorption, separation and life science applications, significant interest has …

Metal–organic framework: An emergent catalyst in C–N cross-coupling reactions

N Diyali, S Rasaily, B Biswas - Coordination Chemistry Reviews, 2022 - Elsevier
Scientific and industrial concern on the rational design of metal–organic frameworks (MOFs)
has marked an escalating trend in recent years and rejuvenated. The emergence of C–N …

Organocatalytic Asymmetric Annulation of ortho‐Alkynylanilines: Synthesis of Axially Chiral Naphthyl‐C2‐indoles

L Peng, K Li, C Xie, S Li, D Xu, W Qin… - Angewandte Chemie …, 2019 - Wiley Online Library
A chiral Brønsted base catalyzed asymmetric annulation of ortho‐alkynylanilines has been
developed to access axially chiral naphthyl‐C2‐indoles via vinylidene ortho‐quinone …

Regioirregular and catalytic Mizoroki–Heck reactions

F Garnes-Portoles, R Greco, J Oliver-Meseguer… - Nature Catalysis, 2021 - nature.com
The palladium-catalysed cross-coupling reaction between alkenes and aryl halides (the
Mizoroki–Heck reaction) is a powerful methodology to construct new carbon–carbon bonds …

[HTML][HTML] Selective semi-hydrogenation of internal alkynes catalyzed by Pd–CaCO3 clusters

J Ballesteros-Soberanas, JC Hernández-Garrido… - Journal of …, 2022 - Elsevier
The de-novo synthesis of soluble or solid-supported Pd-(CaCO 3) n clusters (n= 2–13) and
their high catalytic activity for the semi-hydrogenation of internal alkynes compared to …

Palladium Nanoparticles Supported on Porous Silica Materials as Heterogeneous Catalysts of C− C Coupling and Cross‐Coupling Reactions

Á Mastalir, Á Molnár - ChemCatChem, 2023 - Wiley Online Library
Noble metal nanoparticles supported on porous silica materials represent an important class
of heterogeneous catalysts. Recently, a remarkable progress has been made concerning …

Efficient heterogeneous hydroformylation over zeolite-encaged isolated rhodium ions

W Shang, B Qin, M Gao, X Qin, Y Chai, G Wu… - CCS …, 2023 - chinesechemsoc.org
Alkene hydroformylation is an extremely important industry process currently accomplished
via homogeneous catalysis. Heterogeneous hydroformylation is being avidly pursued as a …

[HTML][HTML] Encapsulation of metal nanoparticle catalysts within mesoporous zeolites and their enhanced catalytic performances: a review

D Xu, H Lv, B Liu - Frontiers in chemistry, 2018 - frontiersin.org
Metal nanoparticles (NPs) exhibit desired activities in various catalytic reactions. However,
the aggregation and sintering of metal NPs usually cause the loss of catalytic performance in …