Zeolites in adsorption processes: State of the art and future prospects

E Pérez-Botella, S Valencia, F Rey - Chemical Reviews, 2022 - ACS Publications
Zeolites have been widely used as catalysts, ion exchangers, and adsorbents since their
industrial breakthrough in the 1950s and continue to be state-of the-art adsorbents in many …

Bimetallic sites for catalysis: from binuclear metal sites to bimetallic nanoclusters and nanoparticles

L Liu, A Corma - Chemical Reviews, 2023 - ACS Publications
Heterogeneous bimetallic catalysts have broad applications in industrial processes, but
achieving a fundamental understanding on the nature of the active sites in bimetallic …

[HTML][HTML] Regulation of the Si/Al ratios and Al distributions of zeolites and their impact on properties

J Li, M Gao, W Yan, J Yu - Chemical Science, 2023 - pubs.rsc.org
Zeolites are typically a class of crystalline microporous aluminosilicates that are constructed
by SiO4 and AlO4 tetrahedra. Because of their unique porous structures, strong Brönsted …

Human-and machine-centred designs of molecules and materials for sustainability and decarbonization

J Peng, D Schwalbe-Koda, K Akkiraju, T Xie… - Nature Reviews …, 2022 - nature.com
Breakthroughs in molecular and materials discovery require meaningful outliers to be
identified in existing trends. As knowledge accumulates, the inherent bias of human intuition …

Intergrowth zeolites, synthesis, characterization, and catalysis

Y Wang, C Tong, Q Liu, R Han, C Liu - Chemical Reviews, 2023 - ACS Publications
Microporous zeolites that can act as heterogeneous catalysts have continued to attract a
great deal of academic and industrial interest, but current progress in their synthesis and …

Controlling nucleation pathways in zeolite crystallization: seeding conceptual methodologies for advanced materials design

R Jain, AJ Mallette, JD Rimer - Journal of the American Chemical …, 2021 - ACS Publications
A core objective of synthesizing zeolites for widespread applications is to produce materials
with properties and corresponding performances that exceed conventional counterparts …

Learning matter: Materials design with machine learning and atomistic simulations

S Axelrod, D Schwalbe-Koda… - Accounts of Materials …, 2022 - ACS Publications
Conspectus Designing new materials is vital for addressing pressing societal challenges in
health, energy, and sustainability. The combination of physicochemical laws and empirical …

The Current Understanding of Mechanistic Pathways in Zeolite Crystallization

AJ Mallette, K Shilpa, JD Rimer - Chemical Reviews, 2024 - ACS Publications
Zeolite catalysts and adsorbents have been an integral part of many commercial processes
and are projected to play a significant role in emerging technologies to address the …

Synthesis strategies to control the Al distribution in zeolites: thermodynamic and kinetic aspects

J Bae, M Dusselier - Chemical Communications, 2023 - pubs.rsc.org
The activity and selectivity of acid-catalyzed chemistry is highly dependent on the Brønsted
and Lewis acid sites generated by Al substitutions in a zeolite framework with the desired …

[HTML][HTML] Machine learning-assisted crystal engineering of a zeolite

X Li, H Han, N Evangelou, NJ Wichrowski, P Lu… - Nature …, 2023 - nature.com
It is shown that Machine Learning (ML) algorithms can usefully capture the effect of
crystallization composition and conditions (inputs) on key microstructural characteristics …