Surface and interface coordination chemistry learned from model heterogeneous metal nanocatalysts: from atomically dispersed catalysts to atomically precise …

W Jing, H Shen, R Qin, Q Wu, K Liu, N Zheng - Chemical Reviews, 2022 - ACS Publications
The surface and interface coordination structures of heterogeneous metal catalysts are
crucial to their catalytic performance. However, the complicated surface and interface …

Metal–support interactions in metal oxide-supported atomic, cluster, and nanoparticle catalysis

D Leybo, UJ Etim, M Monai, SR Bare… - Chemical Society …, 2024 - pubs.rsc.org
Supported metal catalysts are essential to a plethora of processes in the chemical industry.
The overall performance of these catalysts depends strongly on the interaction of adsorbates …

Metal–support interactions in metal/oxide catalysts and oxide–metal interactions in oxide/metal inverse catalysts

Y Li, Y Zhang, K Qian, W Huang - ACS Catalysis, 2022 - ACS Publications
Solid catalysts usually consist of multicomponents, within which interfacial interactions have
been recognized as a key factor affecting structures and catalytic performance. Metal …

p–d Orbital Hybridization Induced by a Monodispersed Ga Site on a Pt3Mn Nanocatalyst Boosts Ethanol Electrooxidation

Y Wang, M Zheng, Y Li, C Ye, J Chen, J Ye… - Angewandte …, 2022 - Wiley Online Library
Constructing monodispersed metal sites in heterocatalysis is an efficient strategy to boost
their catalytic performance. Herein, a new strategy using monodispersed metal sites to tailor …

Heterolytic Dissociation of H2 in Heterogeneous Catalysis

DR Aireddy, K Ding - ACS Catalysis, 2022 - ACS Publications
H2 dissociation plays crucial roles in catalytic hydrogenation reactions and hydrogen
storage. Metal-nanoparticle-based heterogeneous catalysts often dissociate H2 via a …

Electronic oxide–support strong interactions in the graphdiyne-supported cuprous oxide nanocluster catalyst

J Yu, W Chen, F He, W Song, C Cao - Journal of the American …, 2023 - ACS Publications
The interfacial interaction in supported catalysts is of great significance for heterogeneous
catalysis because it can induce charge transfer, regulate electronic structure of active sites …

Surface coordination chemistry of metal nanomaterials

P Liu, R Qin, G Fu, N Zheng - Journal of the American Chemical …, 2017 - ACS Publications
Surface coordination chemistry of nanomaterials deals with the chemistry on how ligands
are coordinated on their surface metal atoms and influence their properties at the molecular …

Atomic Structural Origin of the High Methanol Selectivity over In2O3–Metal Interfaces: Metal–Support Interactions and the Formation of a InOx Overlayer in Ru/In2O3 Catalysts …

N Rui, X Wang, K Deng, J Moncada, R Rosales… - ACS …, 2023 - ACS Publications
CO2 hydrogenation to methanol is of great environmental and economic interest due to its
potential to reduce carbon emissions and produce valuable chemicals in one single …

Approaches for understanding and controlling interfacial effects in oxide-supported metal catalysts

I Ro, J Resasco, P Christopher - ACS Catalysis, 2018 - ACS Publications
Heterogeneous supported metal catalysts are critical for a wide range of chemical
conversion technologies. While the fundamental properties of extended metal surfaces are …

CO2 methanation over Ni nanoparticles inversely loaded with CeO2 and Cr2O3: Catalytic functions of metal oxide/Ni interfaces

J Tian, P Zheng, T Zhang, Z Han, W Xu, F Gu… - Applied Catalysis B …, 2023 - Elsevier
Interfaces between active metal and metal oxide in a heterogenous catalyst often play an
important role in catalysis. In this work, we intentionally synthesized a series of inverse CeO …