Visible‐light photocatalysis: does it make a difference in organic synthesis?

L Marzo, SK Pagire, O Reiser… - Angewandte Chemie …, 2018 - Wiley Online Library
Visible‐light photocatalysis has evolved over the last decade into a widely used method in
organic synthesis. Photocatalytic variants have been reported for many important …

Recent Advances in the Construction of Phosphorus‐Substituted Heterocycles, 2009–2019

L Chen, XY Liu, YX Zou - Advanced Synthesis & Catalysis, 2020 - Wiley Online Library
Phosphorus‐substituted heterocycles represent an important class of organophosphorus
compounds, which not only widely exist in biologically active pharmaceuticals …

Photokatalyse mit sichtbarem Licht: Welche Bedeutung hat sie für die organische Synthese?

L Marzo, SK Pagire, O Reiser, B König - Angewandte Chemie, 2018 - Wiley Online Library
Abstract Die Photokatalyse mit sichtbarem Licht hat sich im letzten Jahrzehnt zu einer breit
angewandten Methode in der organischen Synthese entwickelt. Für viele wichtige …

Phosphine Oxides from a Medicinal Chemist's Perspective: Physicochemical and in Vitro Parameters Relevant for Drug Discovery

P Finkbeiner, JP Hehn, C Gnamm - Journal of Medicinal …, 2020 - ACS Publications
Phosphine oxides and related phosphorus-containing functional groups such as
phosphonates and phosphinates are established structural motifs that are still …

Decarbonylative Phosphorylation of Amides by Palladium and Nickel Catalysis: The Hirao Cross‐Coupling of Amide Derivatives

C Liu, M Szostak - Angewandte Chemie International Edition, 2017 - Wiley Online Library
Considering the ubiquity of organophosphorus compounds in organic synthesis,
pharmaceutical discovery agrochemical crop protection and materials chemistry, new …

Visible-light photo-arbuzov reaction of aryl bromides and trialkyl phosphites yielding aryl phosphonates

RS Shaikh, SJS Düsel, B König - ACS Catalysis, 2016 - ACS Publications
Aryl phosphonates are functional groups frequently found in pharmaceutical and crop
protection agents. For their synthesis via C–P bond formation typically transition-metal …

Cross-Coupling Hydrogen Evolution by Visible Light Photocatalysis Toward C(sp2)–P Formation: Metal-Free C–H Functionalization of Thiazole Derivatives with …

K Luo, YZ Chen, WC Yang, J Zhu, L Wu - Organic letters, 2016 - ACS Publications
Visible light along with 5 mol% eosin B catalyzed the first direct C–H phosphorylation of
thiazole derivatives with diarylphosphine oxides by a photoredox process in the absence of …

Palladium-catalyzed cross-couplings by C–O bond activation

T Zhou, M Szostak - Catalysis science & technology, 2020 - pubs.rsc.org
Although palladium-catalyzed cross-coupling of aryl halides and reactive pseudohalides
has revolutionized the way organic molecules are constructed today across various fields of …

Metal-free direct C–H phosphonation of N-heterocycles with diphenylphosphine oxides under mild conditions

ZN Cai, YP Han, Y Zhang, HY Zhang, J Zhao… - Green …, 2023 - pubs.rsc.org
Herein, metal-free phosphonation of N-heterocycles with diphenylphosphine oxides,
promoted by easily available 1, 5-diazabicyclo [5, 4, 0] undec-5-ene (DBU) in dimethyl …

Photoinduced transition-metal-free cross-coupling of aryl halides with H-phosphonates

H Zeng, Q Dou, CJ Li - Organic letters, 2019 - ACS Publications
Photoinduced transition-metal-and photosensitizer-free cross-coupling of aryl halides
(including Ar–Cl, Ar–Br, and Ar–I) with H-phosphonates (including dialkyl phosphonates and …