Octacyanidometallates for multifunctional molecule-based materials
Octacyanidometallates have been successfully employed in the design of heterometallic
coordination systems offering a spectacular range of desired physical properties with great …
coordination systems offering a spectacular range of desired physical properties with great …
Metallacrowns: supramolecular constructs with potential in extended solids, solution-state dynamics, molecular magnetism, and imaging
JC Lutter, CM Zaleski, VL Pecoraro - Advances in Inorganic Chemistry, 2018 - Elsevier
Metallacrown (MC) research grows each year, in particular with regard to applications of
these molecules. This review will focus on the properties and applications of these …
these molecules. This review will focus on the properties and applications of these …
The Nature of the Bridging Anion Controls the Single-Molecule Magnetic Properties of DyX4M 12-Metallacrown-4 Complexes
TT Boron III, JC Lutter, CI Daly, CY Chow… - Inorganic …, 2016 - ACS Publications
A family of DyX 4 M (12-MC Mn III (N) shi-4) compounds were synthesized and magnetically
characterized (X= salicylate, acetate, benzoate, trimethylacetate, M= NaI or KI). The bridging …
characterized (X= salicylate, acetate, benzoate, trimethylacetate, M= NaI or KI). The bridging …
Magnetic behavior and ground spin states for coordination {L·[M II (Hal) 2] 3} 3− assemblies (Hal= Cl or I) of radical trianion hexacyanohexaazatriphenylenes (L) with …
MV Mikhailenko, VV Ivanov, AF Shestakov… - Dalton …, 2023 - pubs.rsc.org
A series of trianion assemblies of hexaazatriphenylenehexacarbonitrile {HAT (CN) 6} and
hexaazatrinaphthylenehexacarbonitrile {HATNA (CN) 6} with three Fe (II) or Co (II) …
hexaazatrinaphthylenehexacarbonitrile {HATNA (CN) 6} with three Fe (II) or Co (II) …
Regulation of magnetic relaxation behavior by replacing 3d transition metal ions in [M 2 Dy 2] complexes containing two different organic chelating ligands
HS Wang, CL Yin, ZB Hu, Y Chen, ZQ Pan… - Dalton …, 2019 - pubs.rsc.org
Four tetranuclear 3d–4f complexes, namely [Fe2Ln2 (L) 2 (teaH) 2 (Cl) 2](NO3) 2· 4CH3CN
(H2L= N1, N3-bis (3-methoxysalicylidene) diethylenetriamine, teaH3= triethanolamine, Ln …
(H2L= N1, N3-bis (3-methoxysalicylidene) diethylenetriamine, teaH3= triethanolamine, Ln …
A new family of {Co 4 Ln 8} metallacrowns with a butterfly-shaped structure
HG Zhang, YC Du, H Yang, MY Zhuang… - Inorganic Chemistry …, 2019 - pubs.rsc.org
A series of cobalt–lanthanide metallacrowns (MCs){CoIII4Ln8}(Ln= Dy3+ 1, Ho3+ 2 and
Tm3+ 3) based on pyrazinehydroxamic acid (H2pyzha) and pyrazinic acid (Hpyzic) ligands …
Tm3+ 3) based on pyrazinehydroxamic acid (H2pyzha) and pyrazinic acid (Hpyzic) ligands …
Two unprecedented decanuclear heterometallic [Mn II2 Mn III6 Ln III2](Ln= Dy, Tb) complexes displaying relaxation of magnetization
HS Wang, FJ Yang, QQ Long, ZY Huang, W Chen… - Dalton …, 2016 - pubs.rsc.org
We report the syntheses, crystal structures, and magnetic properties of two 3d–4f
heterometallic compounds; namely,[Mn8Ln2O2 (OH) 2 {(py) 2CO2} 4 (teaH) 4 (CH3COO) 6] …
heterometallic compounds; namely,[Mn8Ln2O2 (OH) 2 {(py) 2CO2} 4 (teaH) 4 (CH3COO) 6] …
Synthesis, crystal structures and magnetic properties of a series of pentanuclear heterometallic [Cu II3 Ln III2](Ln= Ho, Dy, and Gd) complexes containing mixed …
Y Chen, QQ Long, ZB Hu, HS Wang… - New Journal of …, 2019 - pubs.rsc.org
In this paper, we present the synthesis, crystal structures and magnetic properties of three
complexes with formulae [Cu3Ln2 (L) 2 (teaH) 2 (N3) 2Cl2]· xCH3CN (H2L= N1, N3-bis (3 …
complexes with formulae [Cu3Ln2 (L) 2 (teaH) 2 (N3) 2Cl2]· xCH3CN (H2L= N1, N3-bis (3 …
Compartmental ligand approach for constructing 3d–4f heterometallic [Cu II 5 Ln III 2] clusters: synthesis and magnetostructural properties
The employment of a reduced Schiff-base ligand, 1, 3-bis (3-methoxy-salicylamino)-2-
propanol (H3L), with the assistance of acetate anions led to the isolation of eight …
propanol (H3L), with the assistance of acetate anions led to the isolation of eight …
Magnetic on–off switching in redox non-innocent ligand bridged binuclear cobalt complexes
Y Wang, J Li, L Zhang, C Chen, R Feng, Y Zhao… - Dalton …, 2018 - pubs.rsc.org
The redox non-innocent ligand 2, 2′-bipyrimidine (bpym) reacted with two molar
equivalents of LCo (tol)(L= CH (MeCNAr) 2, Ar= 2, 6-iPr2C6H3) to afford the binuclear CoII …
equivalents of LCo (tol)(L= CH (MeCNAr) 2, Ar= 2, 6-iPr2C6H3) to afford the binuclear CoII …