The decreasing fossil fuel supply and climate change caused by carbon dioxide emission
have spurred an initiative to develop alternative fuels. Hydrogen is one of the most …

New materials capable of storing hydrogen at high gravimetric and volumetric densities are
required if hydrogen is to be widely employed as a clean alternative to hydrocarbon fuels in …

The coordination chemistry of transition metal hexacyanometallates is a field of continuous
advances and emerging applications. In the last three decades, relevant progress has been …

In recent years, the area dealing with the physical chemistry of materials has become an
emerging discipline in materials science that emphasizes the study of materials for chemical …

The electronic spectra, electrical conductivity, magnetism, and gas adsorption properties of
the newly prepared Prussian blue analogues Fe4 [Ru (CN) 6] 3· 18H2O (2) and K1. 2Ru3. 6 …

Abstract Two Prussian blue analogues (PBAs) Cu II [Fe III (CN) 6)] 2/3· 15H 2 O (1), and KI
Cu II [Fe II (CN) 6)] 3/4· 9H 2 O (2) are synthesised using a co-precipitation method at room …

Within porous Prussian blue to copper the highest H2 storage capacity is observed. Such
behavior finds explanation in the crystal structure for Cu3 [M (CN) 6] 2 with M= Fe, Co, Ir. The …

In open framework Prussian blue analogues, all of the metal atoms linked at the N end of the
CN groups are found at the surface of the cavities with an unsaturated coordination …

The coordination polymer Zn3Na2 [FeII (CN) 6] 2 has an open porous framework that is
stable in acidic and neutral aqueous solutions and appears to be an attractive solid for …

The charge redistribution effects determine the physical and functional properties of
transition metal hexacyanometallates. The π‐back bonding interaction between the CN …