The emerging chemistry of the aluminyl anion
The chemistry of low valent p-block metal complexes continues to elicit interest in the
research community, demonstrating reactivity that replicates and in some cases exceeds …
research community, demonstrating reactivity that replicates and in some cases exceeds …
Cooperation towards nobility: equipping first-row transition metals with an aluminium sword
S Fernández, S Fernando, O Planas - Dalton Transactions, 2023 - pubs.rsc.org
The exploration for noble metals substitutes in catalysis has become a highly active area of
research, driven by the pursuit of sustainable chemical processes. Although the utilization of …
research, driven by the pursuit of sustainable chemical processes. Although the utilization of …
Inducing nucleophilic reactivity at beryllium with an aluminyl ligand
JT Boronski, LR Thomas-Hargreaves… - Journal of the …, 2023 - ACS Publications
The reactions of anionic aluminium or gallium nucleophiles {K [E (NON)]} 2 (E= Al, 1; Ga, 2;
NON= 4, 5-bis (2, 6-diisopropylanilido)-2, 7-di tert-butyl-9, 9-dimethylxanthene) with …
NON= 4, 5-bis (2, 6-diisopropylanilido)-2, 7-di tert-butyl-9, 9-dimethylxanthene) with …
Aluminium (I) anion-supported zero-valent palladium complexes
Monovalent group 13 element anions, such as boryl [BR2]− and aluminyl [AlR2]− anions,
serve as nucleophiles to form diverse group 13 element-containing molecules. Although …
serve as nucleophiles to form diverse group 13 element-containing molecules. Although …
Metal-Ligand Cooperation in Transition Metal-Catalyzed Hydroboration of Polar Unsaturated Organic Groups
S Ataie - 2023 - ruor.uottawa.ca
Metal-Ligand Cooperation (MLC) has been under study over the past two decades as a
powerful tool for small molecule activation and functionalization. However, more mechanistic …
powerful tool for small molecule activation and functionalization. However, more mechanistic …