Hydrogen atom storage upon Z-class borane ligand functions: an alternative approach to ligand cooperation
GR Owen - Chemical Society Reviews, 2012 - pubs.rsc.org
Ligand cooperation has become an important strategy in the development of new transition
metal based transformations. By using this approach some remarkable new catalytic …
metal based transformations. By using this approach some remarkable new catalytic …
Golden jubilee for scorpionates: Recent advances in organometallic chemistry and their role in catalysis
This review aims to describe some recent trends in organometallic complexes containing
scorpionate ligands. Particular attention will be paid to the ligands structure, reagents, and …
scorpionate ligands. Particular attention will be paid to the ligands structure, reagents, and …
Functional group migrations between boron and metal centres within transition metal–borane and–boryl complexes and cleavage of H–H, E–H and E–E′ bonds
GR Owen - Chemical Communications, 2016 - pubs.rsc.org
This feature article examines some of the recent advances in the chemistry of Z-type
transition metal–borane and X-type transition metal–boryl complexes. It focuses on the …
transition metal–borane and X-type transition metal–boryl complexes. It focuses on the …
Diverse reactivity of a tricoordinate organoboron L 2 PhB:(L= oxazol-2-ylidene) towards alkali metal, group 9 metal, and coinage metal precursors
The reactivity of a tricoordinate organoboron L2PhB:(L= oxazol-2-ylidene) 1 towards metal
precursors and its coordination chemistry were comprehensively studied. While the boron …
precursors and its coordination chemistry were comprehensively studied. While the boron …
Double addition of H 2 to transition metal–borane complexes: a 'hydride shuttle'process between boron and transition metal centres
N Tsoureas, YY Kuo, MF Haddow… - Chemical …, 2011 - pubs.rsc.org
Double addition of H 2 to transition metal– borane complexes: a ‘ hydride shuttle’ process
between boron and transition metal centres - Chemical Communications (RSC Publishing) …
between boron and transition metal centres - Chemical Communications (RSC Publishing) …
Synthesis of a rhodium complex featuring the Rh–H–B linkage via a hydride migration from rhodium to borane: study on the electronic deviation induced by the …
H Kameo, H Nakazawa - Organometallics, 2012 - ACS Publications
The rhodium complex [{o-(Ph2P) C6H4} 2 (Ph) BH] Rh (CO)(PPh3)(3-Rh), featuring a B–H–
Rh interaction, was synthesized via phosphine ligand exchange between tris …
Rh interaction, was synthesized via phosphine ligand exchange between tris …
Co-catalysis of a bi-functional ligand containing phosphine and Lewis acidic phosphonium for hydroformylation–acetalization of olefins
YQ Li, P Wang, H Liu, Y Lu, XL Zhao, Y Liu - Green Chemistry, 2016 - pubs.rsc.org
A novel ionic bi-functional ligand of L2 containing a phosphine and a Lewis acidic
phosphonium with I− as the counter-anion was prepared and fully characterized. The …
phosphonium with I− as the counter-anion was prepared and fully characterized. The …
Hemi-and holo-directed lead (II) complexes in a soft ligand environment
M Imran, A Mix, B Neumann, HG Stammler… - Dalton …, 2015 - pubs.rsc.org
To investigate the geometry and stereochemical activity of the lone pair at the lead atom,
lead (II) complexes (1–10) with one tripodal (L1), one dipodal (L2) boron-centred soft ligand …
lead (II) complexes (1–10) with one tripodal (L1), one dipodal (L2) boron-centred soft ligand …
Sequential Migrations between Boron and Rhodium Centers: A Cooperative Process between Rhodium and a Monosubstituted Borohydride Unit
The sodium salt of a monosubstituted borohydride anion containing a 2-mercaptopyridyl unit
(mp) is reported herein. This compound was coordinated to a rhodium (I) center providing …
(mp) is reported herein. This compound was coordinated to a rhodium (I) center providing …
Bifunctional ligands in combination with phosphines and Lewis acidic phospheniums for the carbonylative Sonogashira reaction
C Tan, P Wang, H Liu, XL Zhao, Y Lu… - Chemical …, 2015 - pubs.rsc.org
The combination of phosphine-ligated Pd catalysis and phosphenium (V) Lewis acid
catalysis has been developed for the carbonylative Sonogashira reaction using phosphino …
catalysis has been developed for the carbonylative Sonogashira reaction using phosphino …