Sulfilimines are valuable compounds both in organic synthesis and in pharmaceuticals.
Here we developed a mild and simplified method for preparation of sulfilimines via selective …

The preparation of optically active sulfilimines via the catalytic diastereoselective imination
of sulfides using a chiral nitrene is described. Excellent yields up to 97% and good …

The additive Pummerer reaction of several heteroaromatic sulfilimines has been
investigated. The overall process involves the reaction of the sulfilimine with TFAA to …

The reactions of several aryl-, furanyl-, and vinyl-substituted sulfilimines with dichloroketene
proceeded at 25° C to yield thioalkyl-substituted γ-lactams. The overall process involves …

Reactions between vinyl sulfilimines and dichloroketene generated in situ from
trichloroacetyl chloride in the presence of zinc− copper couple give mixtures of α-dichloro-γ …

The first examples of dihydro-1 H-benzindoles by enantioselective γ-lactamization reaction
of naphthyl sulfilimines with trichloroacetyl chloride in the presence of ZnCu as catalyst (≥ …

Phenyl vinyl sulfones and sulfoxides react with Pd (OAc) 2 to form styryl sulfoxides and
sulfones according to the first Mizoroki− Heck reaction reported for these thio derivatives …

Well‐known and extensively studied for many decades, the Diels‐Alder reaction remains as
one of the most frequently employed synthetic methods for the construction of six‐membered …

Our synthetic methodology, which was previously developed for the preparation of
perfluoroalkyl sulfilimines by a reaction between fluorinated sulfoxides and nitriles, has been …

For the selective synthesis of N-cyano sulfilimines, we have developed a new method based
on the soft–soft interaction between thionium ion electrophiles and cyanonitrene …