Frustrated radical pairs (FRPs) describe the phenomenon that two distinct radicals─ which
would otherwise annihilate each other to form a closed-shell covalent adduct─ can coexist …

BACKGROUND Since the work of Sabatier 100 year ago, chemists have turned almost
exclusively to metals to activate H2 by weakening or cleaving its central bond. This …

Abstract Frustrated Lewis pairs (FLPs) are combinations of Lewis acids and Lewis bases in
solution that are deterred from strong adduct formation by steric and/or electronic factors …

This article is focused on recent developments in main group mediated hydrogenation
chemistry and catalysis using “frustrated Lewis pairs”(FLPs). The broading range of …

The articulation of the notion of “frustrated Lewis pairs”(FLPs), which emerged from the
discovery that H2 can be reversibly activated by combinations of sterically encumbered …

Conspectus Frustrated Lewis pair (FLP) chemistry has emerged in the past decade as a
strategy that enables main-group compounds to activate small molecules. This concept is …

The study of main-group molecules that behave and react similarly to transition-metal (TM)
complexes has attracted significant interest in recent decades. Most notably, the attractive …

The bond activation chemistry of B (C6F5) 3 and related electron-deficient boranes is
currently experiencing a renaissance due to the fascinating development of frustrated Lewis …

Sterically encumbered Lewis acid and Lewis base combinations do not undergo the
ubiquitous neutralization reaction to form “classical” Lewis acid/Lewis base adducts. Rather …

Abstract Der Begriff “frustrierte Lewis‐Paare”(FLPs) bezeichnet Kombinationen von Lewis‐
Säuren und Lewis‐Basen in Lösung, die aufgrund sterischer oder elektronischer Faktoren …