Redox Chemistry and the Role of Trapped Molecular O2 in Li-Rich Disordered Rocksalt Oxyfluoride Cathodes

R Sharpe, RA House, MJ Clarke… - Journal of the …, 2020 - ACS Publications
In the search for high energy density cathodes for next-generation lithium-ion batteries, the
disordered rocksalt oxyfluorides are receiving significant attention due to their high capacity …

An overview of cation-disordered lithium-excess rocksalt cathodes

D Chen, J Ahn, G Chen - ACS Energy Letters, 2021 - ACS Publications
In the past several years, cation-disordered Li-excess rocksalts (DRXs) have quickly
emerged as a new class of promising high-energy Li-ion battery (LIB) cathode materials …

Expandable Li percolation network: the effects of site distortion in cation-disordered rock-salt cathode material

Y Sun, S Jiao, J Wang, Y Zhang, J Liu… - Journal of the …, 2023 - ACS Publications
Cation-disordered rock-salt (DRX) materials receive intensive attention as a new class of
cathode candidates for high-capacity lithium-ion batteries (LIBs). Unlike traditional layered …

A nearly zero-strain li-rich rock-salt oxide with multielectron redox reactions as a cathode for li-ion batteries

K Zhou, Y Li, Y Ha, M Zhang, W Dachraoui… - Chemistry of …, 2022 - ACS Publications
Li-rich oxide cathodes are drawing increasing attention as next-generation cathode
materials for the development of high-energy-density Li-ion batteries due to their strikingly …

Reviewing Li-Rich Disordered Rocksalts as Next-Generation High-Energy Cathode Material

S Guin, S Ghosh, SS Sarkar, U Maitra - Chemistry of Materials, 2024 - ACS Publications
To keep up with the ever increasing demand for improved energy storage technologies,
huge improvements in the capacity and energy density of intercalated cathode materials …

Regulating the anion redox and suppressing the structural distortion of cation-disordered rock-salt cathode materials to improve cycling durability through chlorine …

W Tang, G Zhou, C Hu, A Li, Z Chen… - … Applied Materials & …, 2023 - ACS Publications
Owing to the capacity boost from anion redox activities, cation-disordered rock-salt oxides
are considered as potential candidates for the next-generation of high energy density Li-ion …

Structural Characterization of the Delithiated Noncrystalline Phase in a Li-Rich Li2VO2F Cathode Material

S Hiroi, K Ohara, O Sakata - Chemistry of Materials, 2021 - ACS Publications
As a cathode material for lithium-ion batteries, the disordered rock-salt-type Li2VO2F has a
high theoretical capacity of 462 mA h/g; however, this capacity fades rapidly upon cycling …

Stabilization of Li-rich disordered rocksalt oxyfluoride cathodes by particle surface modification

AJ Naylor, I Kallquist, D Peralta, JF Martin… - ACS applied energy …, 2020 - ACS Publications
Promising theoretical capacities and high voltages are offered by Li-rich disordered rocksalt
oxyfluoride materials as cathodes in lithium-ion batteries. However, as has been discovered …

Crystallographic studies of non-equilibrium structural changes in cathode materials

O Gustafsson - 2022 - diva-portal.org
Crystallographic studies of non-equilibrium structural changes in cathode materials diva-portal.org
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