Linear block copolymer synthesis

H Dau, GR Jones, E Tsogtgerel, D Nguyen… - Chemical …, 2022 - ACS Publications
Block copolymers form the basis of the most ubiquitous materials such as thermoplastic
elastomers, bridge interphases in polymer blends, and are fundamental for the development …

End-functionalized polymers by controlled/living radical polymerizations: synthesis and applications

D Zhou, LW Zhu, BH Wu, ZK Xu, LS Wan - Polymer Chemistry, 2022 - pubs.rsc.org
The precise design of polymers with well-defined end functionality has received great
interest for synthesizing polymeric materials with advanced or distinctive properties. In the …

Living radical polymerization by the RAFT process–a third update

G Moad, E Rizzardo, SH Thang - Australian Journal of Chemistry, 2012 - CSIRO Publishing
This paper provides a third update to the review of reversible deactivation radical
polymerization (RDRP) achieved with thiocarbonylthio compounds (ZC (= S) SR) by a …

Polymer synthesis with more than one form of living polymerization method

X Guo, B Choi, A Feng… - Macromolecular rapid …, 2018 - Wiley Online Library
Controlled radical polymerization (CRP) or controlled/living radical polymerization has
revolutionized the polymer industry as a tool for the preparation of a wide variety of …

Opportunities for dual RDRP agents in synthesizing novel polymeric materials

S Pearson, C St Thomas, R Guerrero-Santos… - Polymer …, 2017 - pubs.rsc.org
Combining reversible-deactivation radical polymerization (RDRP) techniques in a single
system provides access to exciting new polymeric materials which would be difficult to …

Preparation and characterisation of graphene oxide containing block copolymer worm gels

Q Yue, SP Wen, LA Fielding - Soft matter, 2022 - pubs.rsc.org
This paper reports a generic method for preparing reinforced nanocomposite worm-gels.
Aqueous poly (glycerol monomethacrylate)-b-poly (2-hydroxypropyl methacrylate)(PGMA …

Combined nitroxide mediated radical polymerization techniques for block copolymer synthesis

A Kermagoret, D Gigmes - Tetrahedron, 2016 - Elsevier
Nitroxide mediated radical polymerization (NMP) is one of the most powerful method for
advanced polymer synthesis. However, NMP suffers from some limitations, in particular to …

Hydrothiolation of Alkenes and Alkynes Catalyzed by 3, 4‐Dimethyl‐5‐vinylthiazolium iodide and Poly (3, 4‐dimethyl‐5‐vinylthiazolium) iodide

S Chun, J Chung, JE Park, YK Chung - ChemCatChem, 2016 - Wiley Online Library
The highly selective anti‐Markovnikov addition of thiols to unactivated alkenes and alkynes
was demonstrated by using 3, 4‐dimethyl‐5‐vinylthiazolium iodide or its polymer, poly (3, 4 …

Dithioesters in RAFT polymerization

G Moad - RAFT Polymerization: Methods, Synthesis and …, 2021 - Wiley Online Library
This chapter provides a review of the synthesis, properties, and application of dithioesters
with the general structure Z (C S) SR as reversible addition–fragmentation chain transfer …

Alkoxyamine-functionalized latex nanoparticles through RAFT polymerization-induced self-assembly in water

C St Thomas, R Guerrero-Santos, F d'Agosto - Polymer Chemistry, 2015 - pubs.rsc.org
The use of a new symmetrical trithiocarbonate holding two alkoxyamine moieties (I), was
explored in surfactant-free emulsion polymerization of styrene or n-butyl acrylate through …