NMR spectroscopy probes microstructure, dynamics and doping of metal halide perovskites

DJ Kubicki, SD Stranks, CP Grey… - Nature Reviews Chemistry, 2021 - nature.com
Solid-state magic-angle spinning NMR spectroscopy is a powerful technique to probe
atomic-level microstructure and structural dynamics in metal halide perovskites. It can be …

Interfaces in metal halide perovskites probed by solid-state NMR spectroscopy

CJ Dahlman, DJ Kubicki, GNM Reddy - Journal of Materials Chemistry …, 2021 - pubs.rsc.org
Metal halide perovskites (MHPs) are promising light harvesting and emitting materials that
have enabled solar energy conversion efficiencies of over 25% in solution-processed single …

The nature of ion conduction in methylammonium lead iodide: a multimethod approach

A Senocrate, I Moudrakovski, GY Kim… - Angewandte …, 2017 - Wiley Online Library
By applying a multitude of experimental techniques including 1H, 14N, 207Pb NMR and
127I NMR/NQR, tracer diffusion, reaction cell and doping experiments, as well as …

Cation Dynamics in Mixed-Cation (MA)x(FA)1–xPbI3 Hybrid Perovskites from Solid-State NMR

DJ Kubicki, D Prochowicz, A Hofstetter… - Journal of the …, 2017 - ACS Publications
Mixed-cation organic lead halide perovskites attract unfaltering attention owing to their
excellent photovoltaic properties. Currently, the best performing perovskite materials contain …

Local Structure and Dynamics in Methylammonium, Formamidinium, and Cesium Tin(II) Mixed-Halide Perovskites from 119Sn Solid-State NMR

DJ Kubicki, D Prochowicz, E Salager… - Journal of the …, 2020 - ACS Publications
Organic–inorganic tin (II) halide perovskites have emerged as promising alternatives to lead
halide perovskites in optoelectronic applications. While they suffer from considerably poorer …

Persistent dopants and phase segregation in organolead mixed-halide perovskites

BA Rosales, L Men, SD Cady, MP Hanrahan… - Chemistry of …, 2016 - ACS Publications
Organolead mixed-halide perovskites such as CH3NH3PbX3–aX′ a (X, X′= I, Br, Cl) are
interesting semiconductors because of their low cost, high photovoltaic power conversion …

Local Structure in Crystalline, Glass and Melt States of a Hybrid Metal Halide Perovskite

A Singh, D Dayton, DM Ladd, G Reuveni… - Journal of the …, 2024 - ACS Publications
The pursuit of structure–property relationships in crystalline metal halide perovskites (MHPs)
has yielded an unprecedented combination of advantageous characteristics for wide …

Lead halide perovskites: Challenges and opportunities in advanced synthesis and spectroscopy

BA Rosales, MP Hanrahan, BW Boote… - ACS Energy …, 2017 - ACS Publications
Hybrid lead perovskites containing a mixture of organic and inorganic cations and anions
have led to solar cell devices with performance and stability that are better than those of their …

Short-range ion dynamics in methylammonium lead iodide by multinuclear solid state NMR and 127 I NQR

A Senocrate, I Moudrakovski, J Maier - Physical Chemistry Chemical …, 2018 - pubs.rsc.org
We explore the short-range ion dynamics in methylammonium lead iodide (MAPbI3, the
archetypal halide perovskite) by means of solid-state NMR (1H, 13C, 14N, 15N and 207Pb) …

Sensitivity-Enhanced 207Pb Solid-State NMR Spectroscopy for the Rapid, Non-Destructive Characterization of Organolead Halide Perovskites

MP Hanrahan, L Men, BA Rosales, J Vela… - Chemistry of …, 2018 - ACS Publications
Organolead halide and mixed halide perovskites (CH3NH3PbX3, CH3NH3PbX3–n Y n, X
and Y= Cl–, Br–, or I–) are promising materials for photovoltaics and optoelectronic devices …