Nitriles (N≡ CR) are ubiquitous in coordination chemistry, yet literature studies on metal–
nitrile bonding based on a multi-technique approach are rare. We selected an easily …

Various types of Lewis bases have been employed to enhance the performance and stability
of perovskite solar cells (PSCs) by passivating the active layer. The cyano (CN) group is a …

A series of half-sandwich bis (phosphine) ruthenium acetylide complexes [Ru (CCAr)(L2)
Cp′](Ar= phenyl, p-tolyl, 1-naphthyl, 9-anthryl; L2=(PPh3) 2, Cp′= Cp; L2= dppe; Cp …

The spectroelectrochemically generated infrared (IR) and near-infrared spectra of the homo-
bimetallic, hexa-1, 3, 5-triyn-1, 6-diyl-bridged complex cations [{Cp*(dppe) M}(μ-C≡ CC≡ …

Electronic communication between Fe centers in the diiron complexes [{(η 5-Cp)(dppe) Fe}
2 {μ 2-(NC-X-CN)}] n+(n= 0, 2) in which X=[− B10H8−] 2–,− C6H4–,− C8H12–, and …

To investigate the effect of ligand remote (> 10 Å) substituents on the bridging metal center
on the metal‐to‐metal charge transfer (MMCT) properties in cyanidometa‐bridged …

From the reaction of [PtCl2 (N CMe) 2] with FcC N (1)(Fc= Fe (η5-C5H4)(η5-C5H5))
complex [PtCl2 (FcC N)(N CMe)](2) was obtained, which on subsequent treatment with 1 …

A new family of “Fe II (η 5-C 5 H 5)” half sandwich compounds bearing a N-heteroaromatic
ligand coordinated to the iron center by a nitrile functional group has been synthesized and …

Reactions of the vinylidene complexes [M (CCH2)(PP) Cp′] PF6 with NH3 readily afford the
acyclic amino carbene complexes [M {C (Me) NH2}(PP) Cp′] PF6 [M (PP) Cp′= Fe (dppe) …

The structures and luminescent properties of silver (I) complexes with weakly coordinating
nitrile ligands: 1, 4-dicyanobenzene (1, 4-dcb) and 3-cyanopyridine (3-cpy) and nitrite or …