Olefins and alkynes are ubiquitous in transition‐metal catalysis, whether introduced by the
substrate, the catalyst, or as an additive. Whereas the impact of metals and ligands is …

Conspectus The iron–molybdenum cofactor of nitrogenase has unprecedented coordination
chemistry, including a high-spin iron cluster called the iron-molybdenum cofactor (FeMoco) …

Stereochemically defined C-glycosides are prized for their biological activity. Developing a
catalytic method that comprises non-precious metals to synthesize these C-glycosides …

A three-coordinate cobalt (I) complex exhibits high catalytic efficiency and selectivity as well
as good functional group compatibility in alkyne hydrosilylation.[Co (IAd)(PPh3)(CH2TMS)] …

The isomerization of simple terminal alkenes to internal isomers with Z-stereochemistry is
rare, because the more stable E-isomers are typically formed. We show here that cobalt (II) …

The identity and oxidation state of the metal in a coordination compound are typically
thought to be the most important determinants of its reactivity. However, the coordination …

We proposed a reductive elimination/oxidative addition (re/oa) mechanism for reduction of
N2 to 2NH3 by nitrogenase, based on identification of a freeze-trapped intermediate of the α …

For a long time, π-complexes of gold in any of its oxidation states were considered elusive
species of uncertain stoichiometry, low stability, and limited relevance. The recent upsurge …

β-Diketiminates are widely used supporting ligands for building a range of metal complexes
with different oxidation states, structures, and reactivities. This Perspective summarizes the …

Reaction of ferrocene with lithium in the presence of either ethylene or COD allows the Fe
(0)-ate complexes 1 and 4 to be prepared on a large scale, which turned out to be excellent …