Bimetallic sites for catalysis: from binuclear metal sites to bimetallic nanoclusters and nanoparticles

L Liu, A Corma - Chemical Reviews, 2023 - ACS Publications
Heterogeneous bimetallic catalysts have broad applications in industrial processes, but
achieving a fundamental understanding on the nature of the active sites in bimetallic …

Confining isolated atoms and clusters in crystalline porous materials for catalysis

L Liu, A Corma - Nature Reviews Materials, 2021 - nature.com
Abstract Structure–reactivity relationships for nanoparticle-based catalysts have been
greatly influenced by the study of catalytic materials with either supported isolated metal …

Carbon-based single-atom catalysts for advanced applications

MB Gawande, P Fornasiero, R Zbořil - Acs Catalysis, 2020 - ACS Publications
Carbon-based materials are widely employed as metal-free catalysts or supports in
catalysis, energy, and ecological applications because of their interesting properties …

Atomically precise noble metal nanoclusters as efficient catalysts: a bridge between structure and properties

Y Du, H Sheng, D Astruc, M Zhu - Chemical reviews, 2019 - ACS Publications
Improving the knowledge of the relationship between structure and properties is
fundamental in catalysis. Recently, researchers have developed a variety of well-controlled …

Metal catalysts for heterogeneous catalysis: from single atoms to nanoclusters and nanoparticles

L Liu, A Corma - Chemical reviews, 2018 - ACS Publications
Metal species with different size (single atoms, nanoclusters, and nanoparticles) show
different catalytic behavior for various heterogeneous catalytic reactions. It has been shown …

Cu and Cu-based nanoparticles: synthesis and applications in catalysis

MB Gawande, A Goswami, FX Felpin, T Asefa… - Chemical …, 2016 - ACS Publications
The applications of copper (Cu) and Cu-based nanoparticles, which are based on the earth-
abundant and inexpensive copper metal, have generated a great deal of interest in recent …

Applications of single-atom catalysts

Q Zhang, J Guan - Nano Research, 2022 - Springer
Owning to unsaturated coordination environment, quantum size effect and metal-support
interaction, single-or dual-atom metal sites, such as Mn, Fe, Co, Ni, Cu, Zn, Mo, Ru, Rh, Pd …

Functionalized mesoporous SBA-15 silica: recent trends and catalytic applications

P Verma, Y Kuwahara, K Mori, R Raja, H Yamashita - Nanoscale, 2020 - pubs.rsc.org
The development of advanced materials for heterogeneous catalytic applications requires
fine control over the synthesis and structural parameters of the active site. Mesoporous silica …

New strategies for the preparation of sinter‐resistant metal‐nanoparticle‐based catalysts

L Wang, L Wang, X Meng, FS Xiao - Advanced Materials, 2019 - Wiley Online Library
Supported metal nanoparticles are widely used as catalysts in the industrial production of
chemicals, but still suffer from deactivation because of metal leaching and sintering at high …

Catalysis by clusters with precise numbers of atoms

EC Tyo, S Vajda - Nature nanotechnology, 2015 - nature.com
Clusters that contain only a small number of atoms can exhibit unique and often unexpected
properties. The clusters are of particular interest in catalysis because they can act as …