Rotator phases in alkane systems: In bulk, surface layers and micro/nano-confinements

D Cholakova, N Denkov - Advances in colloid and interface science, 2019 - Elsevier
Medium-and long-chain alkanes and their mixtures possess a remarkable physical property–
they form intermediate structured phases between their isotropic liquid phase and their fully …

Structural order in liquids induced by interfaces with crystals

WD Kaplan, Y Kauffmann - Annu. Rev. Mater. Res., 2006 - annualreviews.org
▪ Abstract Interfaces between solids and liquids are important for a range of materials
processes, including soldering and brazing, liquid-phase sintering, crystal growth, and …

Surface layering in ionic liquids: an X-ray reflectivity study

E Sloutskin, BM Ocko, L Tamam… - Journal of the …, 2005 - ACS Publications
The surface structure and thermodynamics of two ionic liquids, based on the 1-alkyl-3-
methylimidazolium cations, were studied by X-ray reflectivity and surface tensiometry. A …

Surface structure of sodium dodecyl sulfate surfactant and oil at the oil-in-water droplet liquid/liquid interface: a manifestation of a nonequilibrium surface state

HB De Aguiar, ML Strader, AGF de Beer… - The journal of physical …, 2011 - ACS Publications
We present sum frequency scattering spectra on kinetically stabilized emulsions consisting
of nanoscopic oil droplets in water, stabilized with sodium dodecyl sulfate (SDS). We have …

Crystallization features of normal alkanes in confined geometry

Y Su, G Liu, B Xie, D Fu, D Wang - Accounts of chemical research, 2014 - ACS Publications
How polymers crystallize can greatly affect their thermal and mechanical properties, which
influence the practical applications of these materials. Polymeric materials, such as block …

Rheological properties of rotator and crystalline phases of alkanes

D Cholakova, K Tsvetkova, S Tcholakova… - Colloids and Surfaces A …, 2022 - Elsevier
Linear long-chain organic molecules are known to form lamellar intermediate phases (called
also rotator phases) between their fully ordered crystalline phases and their isotropic liquid …

Crystallization-induced network formation of tri-and monopalmitin at the middle-chain triglyceride oil/air interface

K Mishra, J Bergfreund, P Bertsch, P Fischer… - Langmuir, 2020 - ACS Publications
Crystalline glycerides play an important role in the formation of multiphase systems such as
emulsions and foams. The stabilization of oil/water interfaces by glyceride crystals has been …

Surface freezing of chain molecules at the liquid–liquid and liquid–air interfaces

E Sloutskin, CD Bain, BM Ocko, M Deutsch - Faraday discussions, 2005 - pubs.rsc.org
Surface freezing (SF) is the formation of a crystalline monolayer at the free surface of a melt
at a temperature Ts, a few degrees above the bulk freezing temperature, Tb. This effect, ie …

Modification of deeply buried hydrophobic interfaces by ionic surfactants

L Tamam, D Pontoni, Z Sapir, S Yefet… - Proceedings of the …, 2011 - National Acad Sciences
Hydrophobicity, the spontaneous segregation of oil and water, can be modified by
surfactants. The way this modification occurs is studied at the oil–water interface for a range …

Wetting, mixing, and phase transitions in Langmuir-Gibbs films

E Sloutskin, Z Sapir, CD Bain, Q Lei, KM Wilkinson… - Physical review …, 2007 - APS
Millimolar bulk concentrations of the surfactant cetyltrimethylammonium bromide (CTAB)
induce spreading of alkanes, H (CH 2) n H (denoted C n) 12≤ n≤ 21, on the water surface …