Catalytic transformation of ubiquitous C–H bonds into valuable C–N bonds offers an efficient
synthetic approach to construct N-functionalized molecules. Over the last few decades …

Conspectus Catalytic reactions that construct carbon–nitrogen bonds are one of central
themes in both synthetic and medicinal chemistry since the obtainable nitrogen-containing …

In recent years, transition‐metal‐catalyzed C− H activation has become a key strategy in the
field of organic synthesis. Rhodium complexes are widely used as catalysts in a variety of …

Transition metal-catalyzed direct functionalization of C–H bonds is one of the key emerging
strategies that is currently attracting tremendous attention with the aim to provide alternative …

Conspectus Owing to the prevalence of nitrogen-containing compounds in functional
materials, natural products and important pharmaceutical agents, chemists have actively …

Transformations of aromatic compounds into the corresponding amines, amides, and imides
through carbon–hydrogen (C–H) bond functionalization represent one of the most step-and …

Towards “Oxidative-Ullmann–Goldberg” and “Oxidative-Buchwald–Hartwig” type amination
reactions. This review focuses on the newly developed oxidative C–N bond formation …

Abstract (Pentamethylcyclopentadienyl) rhodium (RhCp*)‐catalyzed C H transformations
have emerged as a prosperous field in C H bond activation. Recent advances in this area …

The use of directing groups has proven to be a successful strategy to enhance reactivity and
control selectivity in C–H functionalization reactions. In the past decade, a multitude of new …

Mechanistic investigations on the Cp* Rh (III)-catalyzed direct C–H amination reaction led us
to reveal the new utility of 1, 4, 2-dioxazol-5-one and its derivatives as highly efficient amino …