It is well-known that the solvent can strongly influence the course, rate, and equilibrium
position of many chemical reactions. 1, 2 The position and intensity of the bands in the …

Vibrational strong coupling (VSC) occurs when molecular vibrations hybridize with the
modes of an optical cavity, an interaction mediated by vacuum fluctuations. VSC has been …

Now in its 4th edition, this book remains the ultimate reference for all questions regarding
solvents and solvent effects in organic chemistry. Retaining its proven concept, there is no …

The third edition of this besteller covers the latest advancements in this rapidly growing field.
Focusing on analyses and critical evaluation of the subject, this new edition reviews the …

This short overview describes the historical development of the physics and chemistry of
organic solvents and solutions from the alchemist era until the present time based on some …

The solvent polarity parameter ET (30) is newly measured from the solvatochromism of the
betaine dye 30 for 84 solvents and re‐measured for 186 additional ones. The results are …

Solvation is a complex phenomenon involving electrostatic and van der Waals forces as well
as chemically more specific effects such as hydrogen bonding. To disentangle global …

The UV/Vis spectra of a hypothetical negative solvatochromic dye in a solvent are
theoretically calculated assuming the classical damped harmonic oscillator model and the …

A range of methods for the computational prediction of experimentally derived α and β
Kamlet–Taft parameters, indicators of hydrogen bond (H-bond) acidity and basicity for ionic …

The multifaceted potentialities of expanded pyridiniums (EPs), based on one pyridinium core
bearing a 4-pyridyl or 4-pyridylium as the N-pyridinio group, are established at both …