Enzymes as green catalysts for precision macromolecular synthesis

S Shoda, H Uyama, J Kadokawa, S Kimura… - Chemical …, 2016 - ACS Publications
The present article comprehensively reviews the macromolecular synthesis using enzymes
as catalysts. Among the six main classes of enzymes, the three classes, oxidoreductases …

Synthesis, properties and biomedical applications of hydrolytically degradable materials based on aliphatic polyesters and polycarbonates

RP Brannigan, AP Dove - Biomaterials science, 2017 - pubs.rsc.org
Polyester-based polymers represent excellent candidates in synthetic biodegradable and
bioabsorbable materials for medical applications owing to their tailorable properties. The …

Biodegradable High‐Density Polyethylene‐like Material

M Eck, ST Schwab, TF Nelson, K Wurst… - Angewandte …, 2023 - Wiley Online Library
We report a novel polyester material generated from readily available biobased 1, 18‐
octadecanedicarboxylic acid and ethylene glycol possesses a polyethylene‐like solid‐state …

Long-chain aliphatic polymers to bridge the gap between semicrystalline polyolefins and traditional polycondensates

F Stempfle, P Ortmann, S Mecking - Chemical reviews, 2016 - ACS Publications
Other than their established short-chain congeners, polycondensates based on long-chain
difunctional monomers are often dominated by the long methylene sequences of the repeat …

[HTML][HTML] Functional biodegradable polymers via ring-opening polymerization of monomers without protective groups

G Becker, FR Wurm - Chemical society reviews, 2018 - pubs.rsc.org
Biodegradable polymers are of current interest and chemical functionality in such materials
is often demanded in advanced biomedical applications. Functional groups often are not …

Synthesis of biodegradable polymers from renewable resources

MJL Tschan, E Brulé, P Haquette, CM Thomas - Polymer Chemistry, 2012 - pubs.rsc.org
The vast majority of commodity materials are obtained from fossil fuels. However, many
studies predict that all fossil resources will be depleted within a few centuries. Biomass …

Enzymatic polymer synthesis: an opportunity for green polymer chemistry

S Kobayashi, A Makino - Chemical reviews, 2009 - ACS Publications
Polymeric materials, natural and unnatural, are indispensable to the modern society. They
are widely used from everyday life usages as commodity materials to industry and …

Enzymatic polymerization

S Kobayashi, H Uyama, S Kimura - Chemical reviews, 2001 - ACS Publications
There has been an exponential increase in interest in the area of in vitro enzyme-catalyzed
organic reactions, since many families of enzymes can be utilized for transformation of not …

[HTML][HTML] Ultra-strong long-chain polyamide elastomers with programmable supramolecular interactions and oriented crystalline microstructures

L Song, T Zhu, L Yuan, J Zhou, Y Zhang… - Nature …, 2019 - nature.com
Polyamides are one of the most important polymers. Long-chain aliphatic polyamides could
bridge the gap between traditional polyamides and polyethylenes. Here we report an …

A review on enzymatic polymerization to produce polycondensation polymers: The case of aliphatic polyesters, polyamides and polyesteramides

A Douka, S Vouyiouka, LM Papaspyridi… - Progress in Polymer …, 2018 - Elsevier
Enzymatic polymerization represents today an effective and preferable alternative to
conventional chemically-catalyzed processes. It offers significant advantages, summarized …