Cluster-based single-molecule magnets

CJ Milios, REP Winpenny - Molecular Nanomagnets and Related …, 2015 - Springer
This review covers single-molecule magnets, not only focussing on developments since
2005 but also including coverage of earlier work where necessary for understanding of …

Coordination clusters of 3d-metals that behave as single-molecule magnets (SMMs): synthetic routes and strategies

D Maniaki, E Pilichos, SP Perlepes - Frontiers in Chemistry, 2018 - frontiersin.org
The area of 3d-metal coordination clusters that behave as Single-Molecule Magnets (SMMs)
is now quite mature within the interdisciplinary field of Molecular Magnetism. This area has …

Toward a Magnetostructural Correlation for a Family of Mn6 SMMs

CJ Milios, R Inglis, A Vinslava, R Bagai… - Journal of the …, 2007 - ACS Publications
We have structurally and magnetically characterized a total of 12 complexes based on the
Single-Molecule Magnet (SMM)[MnIII6O2 (sao) 6 (O2CH) 2 (MeOH) 4](1)(where sao2-is the …

Controlled association of single-molecule magnets (SMMs) into coordination networks: towards a new generation of magnetic materials

IR Jeon, R Clérac - Dalton transactions, 2012 - pubs.rsc.org
The field of molecular magnetism has rapidly expanded since the discovery of single-
molecule magnets (SMMs) at the beginning of the 1990s. Numerous SMMs have been …

“Switching on” the properties of single-molecule magnetism in triangular manganese (III) complexes

TC Stamatatos, D Foguet-Albiol, SC Lee… - Journal of the …, 2007 - ACS Publications
The reaction between oxide-centered, triangular [MnIII3O (O2CR) 6 (py) 3](ClO4)(R= Me (1),
Et (2), Ph (3)) compounds and methyl 2-pyridyl ketone oxime (mpkoH) affords a new family …

A single-molecule magnet with a “twist”

CJ Milios, A Vinslava, PA Wood… - Journal of the …, 2007 - ACS Publications
A Single-Molecule Magnet with a “Twist” | Journal of the American Chemical Society ACS ACS
Publications C&EN CAS Find my institution Log In Journal of the American Chemical Society …

Trinuclear Heterobimetallic Ni2Ln complexes [L2Ni2Ln][ClO4](Ln= La, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, and Er; LH3=(S) P [N (Me) N CH− C6H3-2-OH-3-OMe] 3) …

V Chandrasekhar, BM Pandian… - Inorganic …, 2008 - ACS Publications
The reaction of LH3 with Ni (ClO4) 2· 6H2O and lanthanide salts in a 2: 2: 1 ratio in the
presence of triethylamine leads to the formation of the trinuclear complexes …

Spin switching via targeted structural distortion

CJ Milios, A Vinslava, W Wernsdorfer… - Journal of the …, 2007 - ACS Publications
The deliberate “stepwise” structural distortion of the [MnIII6O2 (sao) 6 (O2CR) 2L4](S= 4, U
eff= 28 K) family of SMMs (where sao2-is the dianion of salicylaldoxime or 2 …

Azide groups in higher oxidation state manganese cluster chemistry: from structural aesthetics to single-molecule magnets

TC Stamatatos, G Christou - Inorganic chemistry, 2009 - ACS Publications
This Forum Article overviews the recent amalgamation of two long-established areas,
manganese/oxo coordination cluster chemistry involving the higher MnII/MnIV oxidation …

Twisted molecular magnets

R Inglis, CJ Milios, LF Jones, S Piligkos… - Chemical …, 2012 - pubs.rsc.org
The use of derivatised salicylaldoximes in manganese chemistry has led to the synthesis of
a family of approximately fifty hexanuclear ([MnIII6]) and thirty trinuclear ([MnIII3]) Single …