This review article will consider the preparation and application of ynones in synthetic
organic chemistry. Concerning the preparation of these bifunctional compounds, several …

Homogeneous catalysts often show high activity and selectivity towards the various
chemical transformations. Most of the transition metal‐based active catalysts are expensive …

This work reports tert-butyl nitrite (TBN) as a multitask reagent for (1) the controlled synthesis
of N-nitrosoamide from N-alkyl amides,(2) hydrolysis of N-methoxyamides to carboxylic …

The ever-growing interest in the cross-coupling reaction and its applications has increased
exponentially in the last decade, owing to its efficiency and effectiveness. Transition metal …

In this work, we have described the carbonylative synthesis of amides from aryl iodides and
tertiary amines as an aminal source via oxidant‐free C (sp3)− N bond cleavage using in situ …

Palladium nanoparticles (NP) immobilized on metal scavengers (Smopex®-234, Smopex®-
111, PVPy, 1% w/w) have been tested in the acyl Sonogashira reactions between terminal …

This work documents the first palladium pincer complex-catalyzed carbonylative
Sonogashira (CS) and carbonylative Suzuki–Miyaura (CSM) cross-coupling. Compared to …

Palladium-catalyzed carbonylation reaction has surfaced as a robust tool for insertion of the
carbonyl group into organic molecules, and in the last decades enormous progress has …

Ynones are important skeletons in bioactive molecules and valuable building blocks for
organic synthesis, thus great efforts have been devoted to their preparation. While …

Bioinspired supramolecular architectures were used to compartmentalize highly charged
aqua scandium ions into chiral hydrophobic scaffolds for Lewis acid‐catalyzed asymmetric …