Operando Electron Microscopy of Catalysts: The Missing Cornerstone in Heterogeneous Catalysis Research?

SW Chee, T Lunkenbein, R Schlögl… - Chemical …, 2023 - ACS Publications
Heterogeneous catalysis in thermal gas-phase and electrochemical liquid-phase chemical
conversion plays an important role in our modern energy landscape. However, many of the …

Dynamic behavior of metal nanoparticles for catalysis

Y Zhou, C Jin, Y Li, W Shen - Nano Today, 2018 - Elsevier
The geometrical and electronic properties of the active sites on the surface of metal
nanoparticles and their structure evolution and dynamic behavior during catalysis, consitute …

Complete electron economy by pairing electrolysis with hydrogenation

RS Sherbo, RS Delima, VA Chiykowski, BP MacLeod… - Nature Catalysis, 2018 - nature.com
Electrosynthesis provides a method of driving organic reaction chemistry under ambient
conditions with electricity. Pairing two reactions together enables the synthesis of two …

Dynamics of heterogeneous catalytic processes at operando conditions

X Shi, X Lin, R Luo, S Wu, L Li, ZJ Zhao, J Gong - JACS Au, 2021 - ACS Publications
The rational design of high-performance catalysts is hindered by the lack of knowledge of
the structures of active sites and the reaction pathways under reaction conditions, which can …

Achieving high selectivity for alkyne hydrogenation at high conversions with compositionally optimized PdAu nanoparticle catalysts in raspberry colloid-templated …

M Luneau, T Shirman, AC Foucher, K Duanmu… - ACS …, 2019 - ACS Publications
Improving the selectivity for catalytic hydrogenation of alkynes is a key step in upgrading
feedstocks for olefin polymerization. Herein, dilute Pd x Au1–x alloy nanoparticles …

Bridging the gap between the X-ray absorption spectroscopy and the computational catalysis communities in heterogeneous catalysis: a perspective on the current …

R Rana, FD Vila, AR Kulkarni, SR Bare - ACS Catalysis, 2022 - ACS Publications
X-ray absorption spectroscopy (XAS)[extended X-ray absorption fine structure (EXAFS) and
X-ray absorption near-edge structure (XANES)] is a key technique within the heterogeneous …

Metal–organic framework-and polyoxometalate-based sorbents for the uptake and destruction of chemical warfare agents

TG Grissom, AM Plonka, CH Sharp… - … applied materials & …, 2020 - ACS Publications
The threat of chemical warfare agents (CWAs), assured by their ease of synthesis and
effectiveness as a terrorizing weapon, will persist long after the once-tremendous stockpiles …

Structural and valence state modification of cobalt in CoPt nanocatalysts in redox conditions

AC Foucher, N Marcella, JD Lee, DJ Rosen… - ACS …, 2021 - ACS Publications
Platinum is the primary catalyst for many chemical reactions in the field of heterogeneous
catalysis. However, platinum is both expensive and rare. Therefore, it is advantageous to …

In situ and operando electron microscopy in heterogeneous catalysis—insights into multi-scale chemical dynamics

SW Chee, T Lunkenbein, R Schlögl… - Journal of Physics …, 2021 - iopscience.iop.org
This review features state-of-the-art in situ and operando electron microscopy (EM) studies
of heterogeneous catalysts in gas and liquid environments during reaction. Heterogeneous …

Identifying dynamic structural changes of active sites in Pt–Ni bimetallic catalysts using multimodal approaches

D Liu, Y Li, M Kottwitz, B Yan, S Yao, A Gamalski… - ACS …, 2018 - ACS Publications
Alloy nanoparticle catalysts are known to afford unique activities that can differ markedly
from their parent metals, but there remains a generally limited understanding of the nature of …