Effects of the electronic spin transitions of iron in lower mantle minerals: Implications for deep mantle geophysics and geochemistry
We have critically reviewed and discussed currently available information regarding the spin
and valence states of iron in lower mantle minerals and the associated effects of the spin …
and valence states of iron in lower mantle minerals and the associated effects of the spin …
Inelastic x-ray scattering by electronic excitations under high pressure
Investigating electronic structure and excitations under extreme conditions gives access to a
rich variety of phenomena. High pressure typically induces behavior such as magnetic …
rich variety of phenomena. High pressure typically induces behavior such as magnetic …
Spin transition and equations of state of (Mg, Fe) O solid solutions
We have performed a series of experiments to investigate the compositional effect on the
compression behavior of (Mg, Fe) O solid solutions at high pressure. The in‐situ synchrotron …
compression behavior of (Mg, Fe) O solid solutions at high pressure. The in‐situ synchrotron …
Another mechanism for the insulator-metal transition observed in Mott insulators
AG Gavriliuk, VV Struzhkin, IS Lyubutin… - Physical Review B …, 2008 - APS
The two widely accepted mechanisms of the insulator-metal Mott–Hubbard transitions which
have been considered up until now are driven by the band-filling or bandwidth effects. We …
have been considered up until now are driven by the band-filling or bandwidth effects. We …
Elastic anomalies in a spin-crossover system: Ferropericlase at lower mantle conditions
The discovery of a pressure induced iron-related spin crossover in Mg (1-x) Fe x O
ferropericlase (Fp) and Mg-silicate perovskite, the major phases of Earth's lower mantle, has …
ferropericlase (Fp) and Mg-silicate perovskite, the major phases of Earth's lower mantle, has …
Thermal equation of state of lower‐mantle ferropericlase across the spin crossover
The thermal equation of state of ferropericlase [(Mg0. 75Fe0. 25) O] has been investigated
by synchrotron X‐ray diffraction up to 140 GPa and 2000 K in a laser‐heated diamond anvil …
by synchrotron X‐ray diffraction up to 140 GPa and 2000 K in a laser‐heated diamond anvil …
Diamond formation in the deep lower mantle: a high-pressure reaction of MgCO3 and SiO2
Diamond is an evidence for carbon existing in the deep Earth. Some diamonds are
considered to have originated at various depth ranges from the mantle transition zone to the …
considered to have originated at various depth ranges from the mantle transition zone to the …
Sequential Spin State Transition and Intermetallic Charge Transfer in PbCoO3
Z Liu, Y Sakai, J Yang, W Li, Y Liu, X Ye… - Journal of the …, 2020 - ACS Publications
Spin state transitions and intermetallic charge transfers can essentially change material
structural and physical properties while excluding external chemical doping. However, these …
structural and physical properties while excluding external chemical doping. However, these …
Spin crossover in ferropericlase from first-principles molecular dynamics
E Holmström, L Stixrude - Physical review letters, 2015 - APS
Ferropericlase,(Mg, Fe) O, is the second-most abundant mineral of Earth's lower mantle.
With increasing pressure, the Fe ions in the material begin to collapse from a magnetic to …
With increasing pressure, the Fe ions in the material begin to collapse from a magnetic to …