Hydrogen‐atom transfer (HAT) counts amongst the most widely investigated routes to
carbon‐centered radicals. Intramolecular processes involving 1, 5‐HAT are widespread to …

Total synthesis is considered by many as the finest combination of art and science. During
the last decades, several concepts were proposed for achieving the perfect vision of total …

Reported herein is the first visible‐light‐induced formation of alkoxyl radicals from N‐
alkoxyphthalimides, and the Hantzsch ester as the reductant is crucial for the reaction. The …

This work demonstrates how photoredox‐mediated C (sp3)− H activation through radical
translocation can be combined with asymmetric catalysis. Upon irradiation with visible light …

Catalytic enantioselective and diastereoselective spiroketalizations with BINOL-derived
chiral phosphoric acids are reported. The chiral catalyst can override the inherent …

The catalytic asymmetric alkylation of the remote, unactivated δ-position of N-alkyl amides
was enabled by the combination of visible-light-induced proton-coupled electron transfer, 1 …

A novel mild, visible‐light‐induced palladium‐catalyzed hydrogen atom translocation/atom‐
transfer radical cyclization (HAT/ATRC) cascade has been developed. This protocol involves …

An advanced protocol for the intramolecular C–H amination of alkyl groups via amidyl
radicals (Hofmann–Löffler reaction) under homogeneous iodine catalysis is reported. This …

Mechanistic and computational studies were conducted to elucidate the mechanism and the
origins of enantiocontrol for asymmetric chiral phosphoric acid-catalyzed spiroketalization …

The double 1, 3-dipolar cycloaddition of allenoates with nitrilimines has been achieved
under mild reaction conditions, affording a variety of spirobidihydropyrazoles in moderate to …