Understanding chemical reaction mechanisms in ionic liquids: successes and challenges

CD Hubbard, P Illner, R van Eldik - Chemical Society Reviews, 2011 - pubs.rsc.org
The focus of this article is an examination of chemical reaction mechanisms in ionic liquids.
These mechanisms are compared with those pertaining to the same reactions carried out in …

Fundamental signatures of short-and long-range electron transfer for the blue copper protein azurin at Au/SAM junctions

DE Khoshtariya, TD Dolidze… - Proceedings of the …, 2010 - National Acad Sciences
The blue copper protein from Pseudomonas aeruginosa, azurin, immobilized at gold
electrodes through hydrophobic interaction with alkanethiol self-assembled monolayers …

Multiple Mechanisms for Electron Transfer at Metal/Self‐Assembled Monolayer/Room‐Temperature Ionic Liquid Junctions: Dynamical Arrest versus Frictional Control …

DE Khoshtariya, TD Dolidze… - Chemistry–A European …, 2009 - Wiley Online Library
Electrochemical devices consisting of gold electrodes coated by electronically well-behaved
self-assembled alkanethiol monolayers of variable thickness, a ferrocene/ferrocenium redox …

New evidence for a quasi-simultaneous proton-coupled two-electron transfer and direct wiring for glucose oxidase captured by the carbon nanotube–polymer matrix

Y Liu, TD Dolidze, S Singhal… - The Journal of …, 2015 - ACS Publications
Systematic cyclic voltammetry (CV) studies of glucose oxidase (GOx) and its cofactor, flavine
adenine dinucleotide (FAD), almost similarly captured by the matrix of single-walled carbon …

Simplicity within the complexity: Bilateral impact of DMSO on the functional and unfolding patterns of α-chymotrypsin

T Tretyakova, M Shushanyan, T Partskhaladze… - Biophysical …, 2013 - Elsevier
New understanding of the fundamental links between protein stability, conformational
flexibility and function, can be gained through synergic studies on their catalytic and …

High-pressure testing of heterogeneous charge transfer in a room-temperature ionic liquid: Evidence for solvent dynamic control

TD Dolidze, DE Khoshtariya, P Illner… - The Journal of …, 2008 - ACS Publications
We report the first application of a high-pressure electrochemical strategy to study
heterogeneous charge transfer (CT) in a room-temperature ionic liquid,[BMIM][BTA]. High …

Semimetallic TiO 2 nanotubes: new interfaces for bioelectrochemical enzymatic catalysis

D Sarauli, M Riedel, C Wettstein, R Hahn… - Journal of Materials …, 2012 - pubs.rsc.org
Semimetallic TiO 2 nanotubes : new interfaces for bioelectrochemical enzymatic catalysis -
Journal of Materials Chemistry (RSC Publishing) DOI:10.1039/C2JM16427B Royal Society …

Impact of self‐assembly composition on the alternate interfacial electron transfer for electrostatically immobilized cytochrome c

TD Dolidze, S Rondinini, A Vertova… - Biopolymers …, 2007 - Wiley Online Library
(ET) event for cytochrome c (CytC) electrostatically immobilized on carboxyl terminated
groups. We observed biphasic kinetic behavior for a logarithmic dependence of the rate …

Long-range electron transfer with myoglobin immobilized at Au/mixed-SAM junctions: Mechanistic impact of the strong protein confinement

DE Khoshtariya, TD Dolidze… - The Journal of …, 2014 - ACS Publications
Horse muscle myoglobin (Mb) was tightly immobilized at Au-deposited∼ 15-Å-thick mixed-
type (1: 1) alkanethiol SAMs, HS–(CH2) 11–COOH/HS–(CH2) 11–OH, and placed in contact …

Fundamental studies of long-and short-range electron exchange mechanisms between electrodes and proteins

DH Waldeck, DE Khoshtariya - … Nanotechnology in Biology and Medicine I, 2011 - Springer
Electron transfer 1-7 by thermally activated hopping through localized centers is a common
motif that occurs over a broad spectrum of matter such as non-conducting crystalline solids …