Selective three-component reductive alkylalkenylation of unbiased alkenes via carbonyl-directed nickel catalysis
F Wang, S Pan, S Zhu, L Chu - ACS Catalysis, 2022 - ACS Publications
A Ni-catalyzed enantioselective reductive three-component alkylalkenylation of β, γ-alkenyl
ketones with cis-alkenyl iodides and fluoroalkyl iodides in the presence of Mn is reported. By …
ketones with cis-alkenyl iodides and fluoroalkyl iodides in the presence of Mn is reported. By …
Electroreduction Enables Regioselective 1, 2‐Diarylation of Alkenes with Two Electrophiles
W Yu, S Wang, M He, Z Jiang, Y Yu, J Lan… - Angewandte …, 2023 - Wiley Online Library
Precisely introducing two similar functional groups into bulk chemical alkenes represents a
formidable route to complex molecules. Especially, the selective activation of two …
formidable route to complex molecules. Especially, the selective activation of two …
Directed Asymmetric Nickel‐Catalyzed Reductive 1, 2‐Diarylation of Electronically Unactivated Alkenes
Z Dong, Q Tang, C Xu, L Chen, H Ji… - Angewandte Chemie …, 2023 - Wiley Online Library
Abstract Transition‐metal catalyzed intermolecular 1, 2‐diarylation of electronically
unactivated alkenes has emerged as an extensive research topic in organic synthesis …
unactivated alkenes has emerged as an extensive research topic in organic synthesis …
Collaboration as a Key to Advance Capabilities for Earth-Abundant Metal Catalysis
Earth-abundant metal (EAM) catalysis can have profound impact in the pharmaceutical
industry in terms of sustainability and cost improvements from replacing precious metals like …
industry in terms of sustainability and cost improvements from replacing precious metals like …
Three-component asymmetric Ni-catalyzed 1, 2-dicarbofunctionalization of unactivated alkenes via stereoselective migratory insertion
O Apolinar, T Kang, TM Alturaifi… - Journal of the …, 2022 - ACS Publications
An asymmetric 1, 2-dicarbofunctionalization of unactivated alkenes with aryl iodides and
aryl/alkenylboronic esters under nickel/bioxazoline catalysis is disclosed. A wide array of …
aryl/alkenylboronic esters under nickel/bioxazoline catalysis is disclosed. A wide array of …
Nickel‐Catalyzed Regioselective Intermolecular Dialkylation of Alkenylarenes: Generation of Two Vicinal C(sp3)−C(sp3) Bonds Across Alkenes**
We disclose a Ni‐catalyzed regioselective dialkylation reaction of alkenylarenes with α‐
halocarbonyls and alkylzinc reagents. The reaction produces γ‐arylated alkanecarbonyl …
halocarbonyls and alkylzinc reagents. The reaction produces γ‐arylated alkanecarbonyl …
Enantioselective Ni‐Catalyzed Three‐Component Dicarbofunctionalization of Alkenes
Asymmetric multicomponent reactions are considered as efficient protocols for constructing
complex chiral molecules because of their step‐and atom‐economy. Nickel‐catalyzed …
complex chiral molecules because of their step‐and atom‐economy. Nickel‐catalyzed …
Ni-catalyzed regio-and stereoselective alkylarylation of unactivated alkenes in γ, δ-alkenylketimines
We disclose a Ni-catalyzed vicinal alkylarylation of unactivated alkenes in γ, δ-
alkenylketimines with aryl halides and alkylzinc reagents. The reaction produces γ-C (sp3) …
alkenylketimines with aryl halides and alkylzinc reagents. The reaction produces γ-C (sp3) …
Structurally Diverse Bench‐Stable Nickel (0) Pre‐Catalysts: A Practical Toolkit for In Situ Ligation Protocols
A flurry of recent research has centered on harnessing the power of nickel catalysis in
organic synthesis. These efforts have been bolstered by contemporaneous development of …
organic synthesis. These efforts have been bolstered by contemporaneous development of …
Recent Advances in the 1, 2‐Diarylation of Alkenes
Alkenes are a fascinating functional class that can be converted into various structures. A
desirable and durable synthetic method for forming two C− C bonds across an olefin is the …
desirable and durable synthetic method for forming two C− C bonds across an olefin is the …