Topology Matters: Conformation and Microscopic Dynamics of Ring Polymers

M Kruteva, J Allgaier, D Richter - Macromolecules, 2023 - ACS Publications
Ring polymers have fascinated theorists, simulators, and experimentalists as they are the
simplest polymer without ends, giving rise to important topology related properties. We …

Rotaxane Formation of Multicyclic Polydimethylsiloxane in a Silicone Network: A Step toward Constructing “Macro‐Rotaxanes” from High‐Molecular‐Weight Axle and …

M Ebe, A Soga, K Fujiwara, BJ Ree… - Angewandte …, 2023 - Wiley Online Library
Rotaxanes consisting of a high‐molecular‐weight axle and wheel components (macro‐
rotaxanes) have high structural freedom, and are attractive for soft‐material applications …

Structure of Polymer Rings in Linear Matrices: SANS Investigation

M Kruteva, M Monkenbusch, J Allgaier… - …, 2023 - ACS Publications
We have presented a systematic small angle neutron scattering investigation of ring–linear
blends, where we vary either the ring volume fraction for a given ring in a long linear matrix …

Effect of threading on static and dynamic properties of polymer chains in entangled linear-ring blend systems with different stiffness

W Wang, J Lu, R Sun - Polymer, 2024 - Elsevier
Threading is a unique topological state in linear/ring polymer blends (LRB), which is
considered to be essential for evaluating both the static and dynamic properties of ring …

Single-Chain Slip-Spring Simulation for Entangled Ring/Linear Polymer Blends at Low Ring Fractions

Y Tomiyoshi, T Murashima, T Kawakatsu - Macromolecules, 2023 - ACS Publications
We developed a single-chain slip-spring (SCSS) model applicable to entangled ring/linear
polymer blends at low ring volume fractions. The model is based on the following two …

[HTML][HTML] Self-consistent field theory for loop-containing polymers: A general algorithm for path-determination

T Honda, Y Tomiyoshi, T Kawakatsu - Computer Physics Communications, 2024 - Elsevier
An algorithm was developed for self-consistent field theory (SCFT) simulations of loop-
containing polymers (LCPs), where the total number of independent loops (fundamental …

Molecular Dynamics of Topological Barriers on the Crystallization Behavior of Ring Polyethylene Melts with Trefoil Knots

K Hagita, T Murashima, N Sakata, K Shimokawa… - …, 2022 - ACS Publications
Topological barriers in ring polyethylene (PE) melts of trefoil knots inhibit crystallization due
to self-entanglement, as confirmed by united atom molecular dynamics (UAMD) simulations …

Ring-filling effect on stress–strain curves of randomly end-linked tetra-arm prepolymers

K Hagita, T Murashima, T Ohkuma, H Jinnai - Macromolecules, 2022 - ACS Publications
To clarify the stress–strain relation of polymer networks filled with ring polymers, we
investigated randomly end-linked networks produced by a pseudo-crosslinking process of …

Relative chain flexibility determines the spatial arrangement and the diffusion of a single ring chain in linear chain films

JH Choi, T Kwon, BJ Sung - Macromolecules, 2021 - ACS Publications
The flexibility of a single polymer chain, characterized by its persistence length, is
considered to be an intrinsic property of the polymer chain, which determines its …

Terminal relaxation behavior of entangled linear polymers blended with ring and dumbbell-shaped polymers in melts

Y Doi, A Takano, Y Takahashi, Y Matsushita - Rheologica Acta, 2022 - Springer
We investigated the terminal relaxation behavior of entangled linear polystyrene L430 (with
the entanglement number Z= M/M e≃ 24, where M is the molecular weight and M e is the …