N-Heterocyclic Carbenes in Materials Chemistry
N-Heterocyclic carbenes (NHCs) have become one of the most widely studied class of
ligands in molecular chemistry and have found applications in fields as varied as catalysis …
ligands in molecular chemistry and have found applications in fields as varied as catalysis …
N-heterocyclic carbene coordinated metal nanoparticles and nanoclusters
N-heterocyclic carbenes (NHCs) represent one of the most important organic ligands in
coordination chemistry, and have been recently attracting increasing attention in …
coordination chemistry, and have been recently attracting increasing attention in …
A molecular surface functionalization approach to tuning nanoparticle electrocatalysts for carbon dioxide reduction
Conversion of the greenhouse gas carbon dioxide (CO2) to value-added products is an
important challenge for sustainable energy research, and nanomaterials offer a broad class …
important challenge for sustainable energy research, and nanomaterials offer a broad class …
Ultra stable self-assembled monolayers of N-heterocyclic carbenes on gold
CM Crudden, JH Horton, II Ebralidze, OV Zenkina… - Nature …, 2014 - nature.com
Since the first report of thiol-based self-assembled monolayers (SAMs) 30 years ago, these
structures have been examined in a huge variety of applications. The oxidative and thermal …
structures have been examined in a huge variety of applications. The oxidative and thermal …
Carbene ligands in surface chemistry: from stabilization of discrete elemental allotropes to modification of nanoscale and bulk substrates
AV Zhukhovitskiy, MJ MacLeod, JA Johnson - Chemical Reviews, 2015 - ACS Publications
Carbenes are perhaps the most versatile reactive intermediates in chemistry. Since the
original visions of “methylene” by Dumas 1 in 1835 and a generalization of this vision by Nef …
original visions of “methylene” by Dumas 1 in 1835 and a generalization of this vision by Nef …
Immobilization of N-heterocyclic carbene compounds: a synthetic perspective
R Zhong, AC Lindhorst, FJ Groche… - Chemical Reviews, 2017 - ACS Publications
Over the course of the past 15 years the success story of N-heterocyclic carbene (NHC)
compounds in organic, inorganic, and organometallic chemistry has been extended to …
compounds in organic, inorganic, and organometallic chemistry has been extended to …
Halometallate ionic liquids–revisited
J Estager, JD Holbrey… - Chemical Society Reviews, 2014 - pubs.rsc.org
Ionic liquids with chlorometallate anions may not have been the first ionic liquids, however, it
was their development that lead to the recognition that ionic liquids are a distinct, and useful …
was their development that lead to the recognition that ionic liquids are a distinct, and useful …
Addressable carbene anchors for gold surfaces
AV Zhukhovitskiy, MG Mavros… - Journal of the …, 2013 - ACS Publications
New strategies to access functional monolayers could augment current surface modification
methods. Here we present addressable N-heterocyclic carbene (ANHC) anchors for gold …
methods. Here we present addressable N-heterocyclic carbene (ANHC) anchors for gold …
Robust gold nanorods stabilized by bidentate N-heterocyclic-carbene–thiolate ligands
Although N-heterocyclic carbenes (NHCs) have demonstrated outstanding potential for use
as surface anchors, synthetic challenges have limited their application to either large planar …
as surface anchors, synthetic challenges have limited their application to either large planar …
Negatively charged N-heterocyclic carbene-stabilized Pd and Au nanoparticles and efficient catalysis in water
A Ferry, K Schaepe, P Tegeder, C Richter… - ACS …, 2015 - ACS Publications
Herein we describe the synthesis of negatively charged N-heterocyclic carbene (NHC)-
functionalized palladium and gold nanoparticles (NPs), which are stable in water for over 3 …
functionalized palladium and gold nanoparticles (NPs), which are stable in water for over 3 …