Chiral organoboronates have played a critical role in organic chemistry and in the
development of materials science and pharmaceuticals. Much effort has been devoted to …

Conspectus Chain-walking offers extensive opportunities for innovating synthetic methods
that involve constructing chemical bonds at unconventional sites. This approach provides …

Organoboronates represent a cornerstone functional group in modern synthesis owing to
their unique reactivity and divergent synthetic capability. Copper catalysis has become one …

Although known for over 90 years, only in the past two decades has the chemistry of diboron
(4) compounds been extensively explored. Many interesting structural features and reaction …

Regiodivergent alkene functionalization that produces either regioisomer starting from the
same raw materials is desirable. Herein, we report a nickel‐catalyzed switchable site …

Metal-catalyzed regiodivergent reactions allow control over regioselectivity in the synthesis
of a wide range of organic products. Starting from the same material, it is possible to prepare …

Organoboron compounds are valuable synthetic intermediates that find application in a
diverse variety of processes including both C–X and C–C bond-forming transformations …

The oxidation of unactivated C–H bonds has emerged as an effective tactic in natural
product synthesis and has altered how chemists approach the synthesis of complex …

The use of simple and easily available feedstock to quickly and efficiently obtain compounds
with complex molecular structures through the transition-metal-catalyzed construction of C …

Transition metal-catalysed cross-coupling reactions are widely used for construction of
carbon–carbon and carbon–heteroatom bonds. However, compared to aryl or alkenyl …