On the nature of the active species in palladium catalyzed Mizoroki–Heck and Suzuki–Miyaura couplings–homogeneous or heterogeneous catalysis, a critical review

NTS Phan, M Van Der Sluys… - Advanced Synthesis & …, 2006 - Wiley Online Library
A wide array of forms of palladium has been utilized as precatalysts for Heck and Suzuki
coupling reactions over the last 15 years. Historically, nearly every form of palladium used …

Palladium-catalysed reactions of alcohols. Part B: Formation of C–C and C–N bonds from unsaturated alcohols

J Muzart - Tetrahedron, 2005 - Elsevier
The chemistry of alcohols occupies a central place in organic synthesis. Recently, we
reviewed the palladiumcatalysed oxidations of primary and secondary alcohols into their …

Organosulfur Compounds: Electrophilic Reagents in Transition‐Metal‐Catalyzed Carbon–Carbon Bond‐Forming Reactions

SR Dubbaka, P Vogel - Angewandte Chemie International …, 2005 - Wiley Online Library
Transition‐metal‐catalyzed carbon–carbon bond‐forming reactions are among the most
powerful methods in organic synthesis and play a crucial role in modern materials science …

Phosphine-free palladium catalyzed Mizoroki− Heck reaction using hydrazone as a ligand

T Mino, Y Shirae, Y Sasai, M Sakamoto… - The Journal of organic …, 2006 - ACS Publications
Glyoxal bishydrazones 1 and pyridyl-hydrazone 2b were prepared and examined as a
ligand for the Mizoroki− Heck cross-coupling reaction of aryl halides and olefin. We found …

2-Azabicyclo [2.2. 1] hept-5-en-3-one: chemical profile of a versatile synthetic building block and its impact on the development of therapeutics

R Singh, R Vince - Chemical Reviews, 2012 - ACS Publications
Replacement of the furanosyl oxygen with a methylene unit in the ribose sugar in
nucleosides 1 and nucleotides 2 prompted the rise of a new nucleoside class with very …

Digallane with redox-active diimine ligand: Dualism of electron-transfer reactions

IL Fedushkin, AA Skatova, VA Dodonov… - Inorganic …, 2014 - ACS Publications
The reactivity of digallane (dpp-Bian) Ga–Ga (dpp-Bian)(1), which consists of redox-active
ligand 1, 2-bis [(2, 6-diisopropylphenyl) imino] acenaphthene (dpp-Bian), has been studied …

One‐pot syntheses of α, β‐unsaturated carbonyl compounds through palladium‐mediated dehydrogenation of ketones, aldehydes, esters, lactones and amides

J Muzart - European Journal of Organic Chemistry, 2010 - Wiley Online Library
This review highlights the different direct stoichiometric and catalytic palladium procedures
leading to α, β‐unsaturated carbonyl compounds from the corresponding ketones …

Palladium‐Catalyzed Desulfitative Mizoroki–Heck Couplings of Sulfonyl Chlorides with Mono‐and Disubstituted Olefins: Rhodium‐Catalyzed Desulfitative Heck‐Type …

SR Dubbaka, P Vogel - Chemistry–A European Journal, 2005 - Wiley Online Library
New conditions have been found for the desulfitative Mizoroki–Heck arylation and
trifluoromethylation of mono‐and disubustituted olefins with arenesulfonyl and …

N,N-Dimethyl-β-alanine as an Inexpensive and Efficient Ligand for Palladium-Catalyzed Heck Reaction

X Cui, Z Li, CZ Tao, Y Xu, J Li, L Liu, QX Guo - Organic Letters, 2006 - ACS Publications
N, N-Dimethyl-β-alanine was found to be a more powerful phosphine-free ligand than the
previously reported ligand, N, N-dimethylglycine, in the Pd-catalyzed Heck reaction for a …

Tetraethylammonium Salts as Solid, Easy to Handle Ethylene Precursors and Their Application in Mizoroki–Heck Coupling

E Papaplioura, M Mercier, ME Muratore… - The Journal of …, 2024 - ACS Publications
In this study, we introduce a convenient Heck vinylation protocol that eliminates the
requirement for ethylene gas as a coupling partner. In contrast to traditional methodologies …