Frustrated Lewis pair chemistry: development and perspectives

DW Stephan, G Erker - Angewandte Chemie International …, 2015 - Wiley Online Library
Abstract Frustrated Lewis pairs (FLPs) are combinations of Lewis acids and Lewis bases in
solution that are deterred from strong adduct formation by steric and/or electronic factors …

Frustrated Lewis pairs: from concept to catalysis

DW Stephan - Accounts of chemical research, 2015 - ACS Publications
Conspectus Frustrated Lewis pair (FLP) chemistry has emerged in the past decade as a
strategy that enables main-group compounds to activate small molecules. This concept is …

Diverse uses of the reaction of frustrated Lewis pair (FLP) with hydrogen

DW Stephan - Journal of the American Chemical Society, 2021 - ACS Publications
The articulation of the notion of “frustrated Lewis pairs”(FLPs) emerged from the discovery
that H2 can be reversibly activated by combinations of sterically encumbered main group …

Frustrated lewis pairs

DW Stephan - Journal of the American Chemical Society, 2015 - ACS Publications
The articulation of the notion of “frustrated Lewis pairs”(FLPs), which emerged from the
discovery that H2 can be reversibly activated by combinations of sterically encumbered …

Liquid organic and inorganic chemical hydrides for high-capacity hydrogen storage

QL Zhu, Q Xu - Energy & Environmental Science, 2015 - pubs.rsc.org
The search for hydrogen storage materials capable of efficiently storing hydrogen in a
compact and lightweight package is one of the most difficult challenges for the upcoming …

Ammonia–borane and amine–borane dehydrogenation mediated by complex metal hydrides

A Rossin, M Peruzzini - Chemical reviews, 2016 - ACS Publications
This review is a comprehensive survey of the last 10 years of research on ammonia–borane
and amine–borane dehydrogenation mediated by complex metal hydrides (CMHs), within …

Frustrated Lewis pair chemistry of carbon, nitrogen and sulfur oxides

DW Stephan, G Erker - Chemical Science, 2014 - pubs.rsc.org
Frustrated Lewis pairs have been used to activate a variety of small molecules. In this review
we focus on the recent chemistry of FLPs with CO2, CO, N2O, NO and SO2. While FLP …

Chemie frustrierter Lewis‐Paare: Entwicklung und Perspektiven

DW Stephan, G Erker - Angewandte Chemie, 2015 - Wiley Online Library
Abstract Der Begriff “frustrierte Lewis‐Paare”(FLPs) bezeichnet Kombinationen von Lewis‐
Säuren und Lewis‐Basen in Lösung, die aufgrund sterischer oder elektronischer Faktoren …

Reversible H2 Addition across a Nickel–Borane Unit as a Promising Strategy for Catalysis

WH Harman, JC Peters - Journal of the American Chemical …, 2012 - ACS Publications
We report the synthesis and characterization of a series of nickel complexes of the chelating
diphosphine-borane ligands ArB (o-Ph2PC6H4) 2 ([ArDPBPh]; Ar= Ph, Mes). The [ArDPBPh] …

Implementation of cooperative designs in polarized transition metal systems—significance for bond activation and catalysis

B Chatterjee, WC Chang, S Jena, C Werle - ACS Catalysis, 2020 - ACS Publications
Bond activation and catalysis are central to the development of a sustainable energy system.
Frustrated Lewis Pairs have conceptually revolutionized the activation of inert chemical …