[HTML][HTML] Nanostructured titanium dioxide surfaces for electrochemical biosensing

L Bertel, DA Miranda, JM García-Martín - Sensors, 2021 - mdpi.com
TiO2 electrochemical biosensors represent an option for biomolecules recognition
associated with diseases, food or environmental contaminants, drug interactions and related …

[HTML][HTML] Charge transport and energy storage at the molecular scale: from nanoelectronics to electrochemical sensing

PR Bueno, JJ Davis - Chemical Society Reviews, 2020 - pubs.rsc.org
This tutorial review considers how the fundamental quantized properties associated with
charge transport and storage, particularly in molecular films, are linked in a manner that …

On the fundamentals of quantum rate theory and the long-range electron transport in respiratory chains

PR Bueno - Chemical Society Reviews, 2024 - pubs.rsc.org
It has been shown that both the electron-transfer rate constant of an electrochemical reaction
and the conductance quantum are correlated with the concept of quantum capacitance. This …

Quantum mechanical meaning of the charge transfer resistance

YP Sánchez, A Santos, PR Bueno - The Journal of Physical …, 2022 - ACS Publications
In a previous work on the quantum rate interpretation of the electron transfer occurring in
heterogeneous electrochemical interfaces, we demonstrated that a quantum mechanical …

Quantum rate theory and electron-transfer dynamics: A theoretical and experimental approach for quantum electrochemistry

PR Bueno - Electrochimica Acta, 2023 - Elsevier
Quantum rate theory is based on a first-principle quantum mechanical rate concept that
comprises with the Planck–Einstein relationship E= h ν, where ν= e 2/h C q is a frequency …

Quantum rate efficiency of the charge transfer mediated by quantum capacitive states

YP Sánchez, A Santos, PR Bueno - Electrochimica Acta, 2022 - Elsevier
It has been demonstrated that the transfer of electrons between donor and acceptor states is
a room-temperature quantum mechanical event wherein quantum capacitive states per se …

Quantum rate theory for graphene

PR Bueno, DA Miranda Mercado - The Journal of Physical …, 2022 - ACS Publications
The quantum rate theory predicts the electron transfer rate between quantum states
governed by the ratio between the quantum conductance and capacitance (Phys. Chem …

Perspective on quantum electrochemistry. A simple method for measuring the electron transfer rate constant

EVG Alarcón, A Santos, PR Bueno - Electrochimica Acta, 2021 - Elsevier
It was recently shown that the electron transfer rate constant of an electrochemical reaction
and the conductance quantum are correlated with electrochemical capacitance [1]. The …

Electron transfer and conductance quantum

PR Bueno - Physical Chemistry Chemical Physics, 2020 - pubs.rsc.org
The electron transfer rate constant of an electrochemical reaction and the conductance
quantum are fundamental concepts that drive processes ranging from nanoscale electronic …

Ab initio QM/MM simulation of ferrocene homogeneous electron-transfer reaction

MIG Nicholson, PR Bueno… - The Journal of Physical …, 2020 - ACS Publications
Here, we demonstrate the feasibility of hybrid computational methods to predict the
homogeneous electron exchange between the ferrocene and its oxidized (ferrocenium) …