A review on solvent-free methods in organic synthesis

S Zangade, P Patil - Current Organic Chemistry, 2019 - ingentaconnect.com
Most of the synthetic chemical transformation reactions involve the use of different organic
solvents. Unfortunately, some of these toxic solvents are used in chemical laboratory …

Manganese (iii) acetate in organic synthesis: a review of the past decade

J Wang, Y Zhang, Y Zhou, X Gu, B Han… - Organic Chemistry …, 2024 - pubs.rsc.org
Mn (OAc) 3 has emerged as a highly valuable one-electron oxidant in the fields of synthetic
and medicinal chemistry, owing to its mild reactivity, economic feasibility, and low toxicity. In …

The Chameleonic Nature of the Nitro Group Applied to a Base-Promoted Cascade Reaction To Afford Indane-Fused Dihydrofurans

H Díaz-Salazar, JC Rodríguez-Colín… - The Journal of …, 2023 - ACS Publications
We disclose a Michael/Conia-ene/SN2 cascade reaction for the synthesis of Indane-fused
dihydrofurans from 1, 3-dicarbonyl compounds and 2-alkynylnitrostyrenes promoted by …

AlCl3-Catalyzed Cascade Reactions of 1,2,3-Trimethoxybenzene and Adipoyl Chloride: Spectroscopic Investigations and Density Functional Theory Studies

Y Çetinkaya, T Artunç, A Menzek - ACS omega, 2022 - ACS Publications
The reaction of 1, 2, 3-trimethoxybenzene with adipoyl chloride in the presence of AlCl3
gave two isomeric cyclopentene derivatives, 1, 6-bis (2, 3, 4-trimethoxyphenyl) hexane-1, 6 …

Manganese (III) acetate mediated synthesis of polysubstituted pyrroles under solvent-free ball milling

JC Zeng, H Xu, F Yu, Z Zhang - Tetrahedron Letters, 2017 - Elsevier
Under solvent-free ball milling conditions, a simple and mild method was developed for
efficient synthesis of 2, 5-dimethyl-3, 4-dicarboxylate-pyrroles and N-substituted 3, 4 …

Copper‐Oxone Promoted Oxidative C− H Functionalization: Synthesis of 2‐Aminobenzothiazoles and Evaluation of Their Antimicrobial Activities

ŞD Doğan, MG Gündüz, SB Uğur, H Doğan… - …, 2021 - Wiley Online Library
Benzothiazole is one of the most important heterocyclic scaffolds existing in both natural and
synthetic compounds. This prominent ring is of undoubted interest due to its broad range of …

Multidecagram Scale Synthesis of an Endoperoxide, Precursor of Anti-malarial and Anti-leishmanial Agents, via Free-Radical [2 + 2 + 2] Annulation with Molecular …

D Lardani, R Marti, A Quintavalla… - … Process Research & …, 2021 - ACS Publications
From screening experimental parameters to scaling up, a safe approach is reported for the
multidecagram scale preparation of methyl ester of 6, 6-dibutyl-3-hydroxy-3-methyl-1, 2 …

Synthesis of ferrocene substituted dihydrofuran derivatives via manganese (III) acetate mediated radical addition-cyclization reactions

H Aslan, A Öktemer, H Dal, T Hökelek - Tetrahedron, 2017 - Elsevier
In this study, the manganese (III) acetate mediated radical addition-cyclization reactions of
ferrocene substituted alkenes and active methylene compounds were carried out. The regio …

Insight into the intramolecular interactions of trans-2-azidocycloalk-3-en-1-ols and trans-2-azidocycloalk-3-en-1-yl acetates: A theoretical study

Y Çetinkaya, A Maraş, S Göksu - Tetrahedron, 2021 - Elsevier
In this study, dedicated to Prof. Dr. Yaşar Sütbeyaz (1950–2016), intramolecular interactions
in (1S (R), 2S (R))-2-azidocycloalk-3-en-1-ols and (1S (R), 2S (R))-2-azidocycloalk-3-en-1-yl …

Unusual manganese (III)-mediated oxidative free-radical additions of Meldrum's acid and dimethyl malonate to benzonorbornadiene and oxabenzonorbornadiene

R Çalışkan, N Nohut, Ö Yılmaz, E Sahin, M Balci - Tetrahedron, 2017 - Elsevier
Benzonorbornadiene and 7-oxabenzonorbornadiene were reacted with Meldrum's acid and
dimethyl malonate in the presence of Mn (OAc) 3 and Cu (OAc) 2 in acetic acid. The reaction …