Gas-phase reactions of isoprene and its major oxidation products

PO Wennberg, KH Bates, JD Crounse… - Chemical …, 2018 - ACS Publications
Isoprene carries approximately half of the flux of non-methane volatile organic carbon
emitted to the atmosphere by the biosphere. Accurate representation of its oxidation rate and …

Proton-transfer-reaction mass spectrometry: applications in atmospheric sciences

B Yuan, AR Koss, C Warneke, M Coggon… - Chemical …, 2017 - ACS Publications
Proton-transfer-reaction mass spectrometry (PTR-MS) has been widely used to study the
emissions, distributions, and chemical evolution of volatile organic compounds (VOCs) in …

The human oxidation field

N Zannoni, PSJ Lakey, Y Won, M Shiraiwa, D Rim… - Science, 2022 - science.org
Hydroxyl (OH) radicals are highly reactive species that can oxidize most pollutant gases. In
this study, high concentrations of OH radicals were found when people were exposed to …

Seasonal variability and source apportionment of volatile organic compounds (VOCs) in the Paris megacity (France)

A Baudic, V Gros, S Sauvage, N Locoge… - Atmospheric …, 2016 - acp.copernicus.org
Within the framework of air quality studies at the megacity scale, highly time-resolved volatile
organic compound (C 2–C 8) measurements were performed in downtown Paris (urban …

Recent discoveries and future challenges in atmospheric organic chemistry

M Glasius, AH Goldstein - 2016 - ACS Publications
Earth's atmosphere contains a multitude of organic compounds, which differ by orders of
magnitude regarding fundamental properties such as volatility, reactivity, and propensity to …

Atmospheric fates of Criegee intermediates in the ozonolysis of isoprene

TB Nguyen, GS Tyndall, JD Crounse… - Physical Chemistry …, 2016 - pubs.rsc.org
We use a large laboratory, modeling, and field dataset to investigate the isoprene+ O3
reaction, with the goal of better understanding the fates of the C1 and C4 Criegee …

Identifying and correcting interferences to PTR-ToF-MS measurements of isoprene and other urban volatile organic compounds

MM Coggon, CE Stockwell, MS Claflin… - Atmospheric …, 2024 - amt.copernicus.org
Proton-transfer-reaction time-of-flight mass spectrometry (PTR-ToF-MS) is a technique
commonly used to measure ambient volatile organic compounds (VOCs) in urban, rural, and …

Radical chemistry in oxidation flow reactors for atmospheric chemistry research

Z Peng, JL Jimenez - Chemical Society Reviews, 2020 - pubs.rsc.org
Environmental chambers have been playing a vital role in atmospheric chemistry research
for seven decades. In last decade, oxidation flow reactors (OFR) have emerged as a …

Formation of low volatility organic compounds and secondary organic aerosol from isoprene hydroxyhydroperoxide low-NO oxidation

JE Krechmer, MM Coggon, P Massoli… - … science & technology, 2015 - ACS Publications
Gas-phase low volatility organic compounds (LVOC), produced from oxidation of isoprene 4-
hydroxy-3-hydroperoxide (4, 3-ISOPOOH) under low-NO conditions, were observed during …

Formaldehyde production from isoprene oxidation across NOx regimes

GM Wolfe, J Kaiser, TF Hanisco… - Atmospheric …, 2016 - acp.copernicus.org
The chemical link between isoprene and formaldehyde (HCHO) is a strong, nonlinear
function of NO x (ie, NO+ NO 2). This relationship is a linchpin for top-down isoprene …