Mechanistic development and recent applications of the Chan–Lam amination

MJ West, JWB Fyfe, JC Vantourout… - Chemical …, 2019 - ACS Publications
Transition metal-mediated formation of C–N bonds is an essential synthetic methodology.
The discovery of the Chan–Lam amination provided a C–N bond forming process that was …

Tuning metal–metal interactions for cooperative small molecule activation

Q Wang, SH Brooks, T Liu, NC Tomson - Chemical Communications, 2021 - pubs.rsc.org
Cluster complexes have attracted interest for decades due to their promise of drawing
analogies to metallic surfaces and metalloenzyme active sites, but only recently have …

Copper-catalysed difluorocarbene transfer enables modular synthesis

X Zeng, Y Li, QQ Min, XS Xue, X Zhang - Nature Chemistry, 2023 - nature.com
The use of metal catalysts to produce and control the reactivity of carbenes has long offered
a powerful approach to organic synthesis; however, difluorocarbene transfer catalysed by …

Direct functionalization of methane into ethanol over copper modified polymeric carbon nitride via photocatalysis

Y Zhou, L Zhang, W Wang - Nature communications, 2019 - nature.com
Direct valorization of methane to its alcohol derivative remains a great challenge.
Photocatalysis arises as a promising green strategy which could exploit hydroxyl radical …

A small cationic organo–copper cluster as thermally robust highly photo-and electroluminescent material

M Olaru, E Rychagova, S Ketkov… - Journal of the …, 2019 - ACS Publications
Organic light-emitting diodes (OLEDs) are revolutionizing display applications. In this
aspect, luminescent complexes of precious metals such as iridium, platinum, or ruthenium …

Chan–Evans–Lam couplings with copper iminoarylsulfonate complexes: scope and mechanism

V Hardouin Duparc, GL Bano, F Schaper - ACS Catalysis, 2018 - ACS Publications
Copper (II) pyridyliminoarylsulfonate complexes with chloride or triflate counteranions were
employed in Chan–Evans–Lam (CEL) couplings of N-nucleophiles and arylboronic acids …

Dicopper Cu (I) Cu (I) and Cu (I) Cu (II) complexes in copper-catalyzed azide–alkyne cycloaddition

MS Ziegler, KV Lakshmi, TD Tilley - Journal of the American …, 2017 - ACS Publications
A discrete, dicopper μ-alkynyl complex,[Cu2 (μ-η1: η1-C C (C6H4) CH3) DPFN] NTf2
(DPFN= 2, 7-bis (fluoro-di (2-pyridyl) methyl)-1, 8-naphthyridine; NTf2–= N (SO2CF3) 2–) …

Dinuclear Cu(I) molecular electrocatalyst for CO2-to-C3 product conversion

N Sakamoto, K Sekizawa, S Shirai, T Nonaka, T Arai… - Nature Catalysis, 2024 - nature.com
Molecular metal complex catalysts are highly tunable in terms of their CO2 reduction
performance by means of their flexible molecular design. However, metal complex catalysts …

Photo and thermally stable branched corrosion inhibitors containing two benzotriazole groups for copper in 3.5 wt% sodium chloride solution

C Jing, Z Wang, Y Gong, H Huang, Y Ma, H Xie, H Li… - Corrosion …, 2018 - Elsevier
New branched conjugated derivatives with two benzotriazole groups as well as a linear
analog containing one benzotriazole segment used as corrosion inhibitors for copper in 3.5 …

Bimetallics in a nutshell: complexes supported by chelating naphthyridine-based ligands

AN Desnoyer, A Nicolay, P Rios… - Accounts of chemical …, 2020 - ACS Publications
Conspectus Bimetallic motifs are a structural feature common to some of the most effective
and synthetically useful catalysts known, including in the active sites of many …