The synthesis of nitrogen-containing heterocycles, including natural alkaloids and other
compounds presenting different types of biological activities have proved to be successful …

In this account the reactions of chiral N‐tert‐butylsulfinyl imines with organometallic
reagents such as organoalkaline (lithium, sodium, potassium and cesium derivatives) …

The first enantioselective aza‐Darzens reaction of cyclic imines with α‐halogenated ketones
was realized under mild reaction conditions by using amino‐acid‐derived bifunctional …

A novel type of highly efficient chiral sulfinamide bisphosphine catalysts (Wei‐Phos) were
developed. These could be easily prepared from commercially available starting materials …

A general, scalable, and highly diastereoselective aziridination of N-tert-butanesulfinyl
ketimino esters is described. The methodology has been utilized to provide straightforward …

A versatile method for the synthesis of enantioenriched N–H sulfoximines is reported. The
approach stems from the organomagnesium-mediated ring opening of novel cyclic …

Medicinally relevant sulfoximines are accessed from C–S coupling of sulfonimidates and
commercially available organomagnesium reagents. Sulfonimidates are conveniently …

A catalyst-free one-pot three-component method of sulfoxonium ylides, nitrosoarenes, and
alkynes for the synthesis of highly functionalized di-keto aziridines and alkenes is described …

Herein, we report a Zn‐ProPhenol catalyzed aza‐Darzens reaction using chlorinated
aromatic ketones as nucleophilic partners for the efficient and enantioselective construction …

Aziridination of N-sulfonyl imines with α-ketoesters in the presence of P (NMe2) 3 is
reported. Adducts derived from trivalent phosphorus reagents and α-ketoesters are …