Due to the high emissions of CO2 and the related environmental impact, the chemical
transformation of CO2 to useful industrially relevant products or their precursor is of …

During recent years, the catalytic transformation of CO2 using silicon‐hydrides as reductants
has emerged as a promising methodology that allows the selective reduction of CO2 to the …

The formylation and methylation of amines with carbon dioxide and hydrosilanes are
emerging yet important types of transformations for CO2. Catalytic methods effective for both …

Hydrosilanes are useful precursors for the preparation of many different silicon-containing
molecules, and they are transformed into value-added molecules generally through Si–H …

An exciting challenge in transition metal catalyst design is to explore whether earth-
abundant base metals such as Fe, Co, and Ni can mediate two-electron reductive …

The selective reduction of CO2 to the formaldehyde level remains an important challenge
and to date only a few catalysts have been developed for this reaction. Herein, we report an …

Catalytic hydrosilylation of carbon dioxide has emerged as a promising approach for carbon
dioxide utilization. It allows the reductive transformation of carbon dioxide into value‐added …

Carbon dioxide (CO2) was used as a C1 source to prepare silyl formates, formamides, and
aldehydes. Tetrabutylammonium acetate (TBAA) catalyzed the solvent-free N-formylation of …

A simple cooperative catalytic system was successfully developed for the solvent‐free N‐
formylation of amines with CO2 and hydrosilanes under ambient conditions, which was …

Triphenylborane (BPh3) in highly polar, aprotic solvents catalyzes hydrosilylation of CO2
effectively under mild conditions to provide silyl formates with high chemoselectivity (> 95%) …