Ni-Catalyzed Oxygen Transfer from N2O onto sp3-Hybridized Carbons
S Ni, FL Vaillant, A Mateos-Calbet… - Journal of the …, 2022 - ACS Publications
Herein we disclose a catalytic synthesis of cycloalkanols that harnesses the potential of N2O
as an oxygen transfer agent onto sp3-hybridized carbons. The protocol is distinguished by …
as an oxygen transfer agent onto sp3-hybridized carbons. The protocol is distinguished by …
Oxidative Additions of C−F Bonds to the Silanide Anion [Si(C2F5)3]−
N Tiessen, M Keßler, B Neumann… - Angewandte Chemie …, 2022 - Wiley Online Library
Compounds exhibiting main group elements in low oxidation states were found to mimic the
reactivity of transition metal complexes. Like the latter, such main group species show a …
reactivity of transition metal complexes. Like the latter, such main group species show a …
QM/MM Calculations Suggest Concerted O− O Bond Cleavage and Substrate Oxidation by Nonheme Diiron Toluene/o‐Xylene Monooxygenase
TP Zhou, WH Deng, Y Wu… - Chemistry–An Asian …, 2022 - Wiley Online Library
The nonheme diiron toluene/o‐xylene monooxygenase (ToMO) is the most studied toluene
monooxygenase that mediates an aromatic hydroxylation reaction. In this work, QM/MM …
monooxygenase that mediates an aromatic hydroxylation reaction. In this work, QM/MM …
Computational Exploration of Mechanistic Avenues in Metal‐Free CO2 Reduction to CO by Disilyne Bisphosphine Adduct and Phosphonium Silaylide
Recent years have seen a growing interest in metal‐free CO2 activation by silylenes,
silylones, and silanones. However, compared to mononuclear silicon species, CO2 …
silylones, and silanones. However, compared to mononuclear silicon species, CO2 …
Oxidative Addition von C− F‐Bindungen an das Silanid‐Anion [Si (C2F5) 3]−
N Tiessen, M Keßler, B Neumann… - Angewandte …, 2022 - Wiley Online Library
Verbindungen von Hauptgruppenelementen in niedrigen Oxidationsstufen sind in der Lage,
die Reaktivität von Übergangsmetallkomplexen nachzuahmen. Wie Letztere neigen …
die Reaktivität von Übergangsmetallkomplexen nachzuahmen. Wie Letztere neigen …
Studies on Silylated Low-Oxidation State Group 14 Compounds: Synthesis, Structural Properties and Reactivity
T Eisner - 2024 - mediatum.ub.tum.de
Recent research focused on developing environmentally friendly main group catalysts as
alternatives for transition metal catalysts. This work focuses on the influence of silyl …
alternatives for transition metal catalysts. This work focuses on the influence of silyl …