Molecular main group metal hydrides
This review serves to document advances in the synthesis, versatile bonding, and reactivity
of molecular main group metal hydrides within Groups 1, 2, and 12–16. Particular attention …
of molecular main group metal hydrides within Groups 1, 2, and 12–16. Particular attention …
s-Block metal catalysts for the hydroboration of unsaturated bonds
The addition of a B–H bond to an unsaturated bond (polarized or unpolarized) is a powerful
and atom-economic tool for the synthesis of organoboranes. In recent years, s-block …
and atom-economic tool for the synthesis of organoboranes. In recent years, s-block …
Catalytic Dearomatization of N‐Heteroarenes with Silicon and Boron Compounds
Dearomatized N‐heterocycles are an important class of structural motifs for organic
synthesis and chemical biology. The catalytic dearomative reduction of unactivated N …
synthesis and chemical biology. The catalytic dearomative reduction of unactivated N …
Asymmetric Cu-catalyzed 1, 4-dearomatization of pyridines and pyridazines without preactivation of the heterocycle or nucleophile
MW Gribble Jr, S Guo, SL Buchwald - Journal of the American …, 2018 - ACS Publications
We show that a chiral copper hydride (CuH) complex catalyzes C–C bond-forming
dearomatization of pyridines and pyridazines at room temperature. The catalytic reaction …
dearomatization of pyridines and pyridazines at room temperature. The catalytic reaction …
Rhodium-Catalyzed Double Hydroboration of Quinolines
Selective double hydroelementation of N-heteroarenes can be one of the most
straightforward and atom-economic routes toward dearomatized N-heterocycles bearing a …
straightforward and atom-economic routes toward dearomatized N-heterocycles bearing a …
The coordination chemistry of organo-hydride donors: new prospects for efficient multi-electron reduction
A McSkimming, SB Colbran - Chemical Society Reviews, 2013 - pubs.rsc.org
In biological reduction processes the dihydronicotinamides NAD (P) H often transfer hydride
to an unsaturated substrate bound within an enzyme active site. In many cases, metal ions in …
to an unsaturated substrate bound within an enzyme active site. In many cases, metal ions in …
Molecular magnesium hydrides
D Mukherjee, J Okuda - Angewandte Chemie International …, 2018 - Wiley Online Library
Solid magnesium hydride [MgH2]∞ has been pursued as a potential hydrogen‐storage
material. Organic chemists were rather interested in soluble magnesium hydride reagents …
material. Organic chemists were rather interested in soluble magnesium hydride reagents …
A Cationic Calcium Hydride Cluster Stabilized by Cyclen‐Derived Macrocyclic N, N, N, N Ligands
P Jochmann, JP Davin, TP Spaniol, L Maron… - Angewandte Chemie …, 2012 - infona.pl
A Cationic Calcium Hydride Cluster Stabilized by Cyclen‐Derived Macrocyclic N,N,N,N Ligands
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Ring‐Shaped Phosphinoamido‐Magnesium‐Hydride Complexes: Syntheses, Structures, Reactivity, and Catalysis
L Fohlmeister, A Stasch - Chemistry–A European Journal, 2016 - Wiley Online Library
A series of magnesium (II) complexes bearing the sterically demanding phosphinoamide
ligand, L−= Ph2PNDip−, Dip= 2, 6‐diisopropylphenyl, including heteroleptic magnesium …
ligand, L−= Ph2PNDip−, Dip= 2, 6‐diisopropylphenyl, including heteroleptic magnesium …
Ni–O Cooperation versus Nickel(II) Hydride in Catalytic Hydroboration of N-Heteroarenes
An air-stable half-sandwich nickel (II) complex bearing a phosphinophenolato ligand, Cp* Ni
(1, 2-Ph2PC6H4O)(1), has been designed and synthesized for activation of HBpin and …
(1, 2-Ph2PC6H4O)(1), has been designed and synthesized for activation of HBpin and …