Integral equation theory description of phase equilibria in classical fluids

C Caccamo - Physics reports, 1996 - Elsevier
We review the present status of applications of integral equation theories (IETs) for the radial
distribution function g (r), to the determination of phase diagrams and stability conditions of …

Structure and dynamics of molten salts

M Revere, MP Tosi - Reports on Progress in Physics, 1986 - iopscience.iop.org
Modern techniques of liquid state physics have been successfully used to probe the
microscopic structure and dynamics of a variety of multicomponent liquids in which relative …

Criticality in ionic fluids: Debye-Hückel theory, Bjerrum, and beyond

ME Fisher, Y Levin - Physical review letters, 1993 - APS
Debye-Hückel (DH) theory predicts phase separation in the primitive model electrolyte: hard
spheres of diameter a with charges±q. The coexistence curve (CC) is acceptable with T c*≡ …

The story of coulombic critiality

ME Fisher - Journal of statistical physics, 1994 - Springer
Recent experiments on phase separation and criticality in ionic fluids are reviewed briefly.
The data suggest a sharp distinction between solvophobic criticality, displayed by nonionic …

Criticality in the hard-sphere ionic fluid

Y Levin, ME Fisher - Physica A: Statistical Mechanics and its Applications, 1996 - Elsevier
A physically based mean-field theory of criticality and phase separation in the restricted
primitive model of an electrolyte (hard spheres of diameter a carrying charges±q) is …

Phase behavior of the restricted primitive model and square-well fluids from Monte Carlo simulations in the grand canonical ensemble

G Orkoulas, AZ Panagiotopoulos - The Journal of chemical physics, 1999 - pubs.aip.org
Significant methodological progress has been made over the years in the development of
Monte Carlo algorithms capable of predicting phase equilibrium properties for model …

Criticality and phase transitions in ionic fluids

G Stell - Journal of statistical physics, 1995 - Springer
Recent experimental investigations of criticality and phase separation in ionic fluids have
revealed behavior of great theoretical interest. In seeking to understand the experiments …

Free energy and phase equilibria for the restricted primitive model of ionic fluids from Monte Carlo simulations

G Orkoulas, AZ Panagiotopoulos - The Journal of chemical physics, 1994 - pubs.aip.org
In this work, we investigate the liquid-vapor phase transition of the restricted primitive model
of ionic fluids. We show that at the low temperatures where the phase transition occurs, the …

Non-aqueous electrolyte solutions in chemistry and modern technology

J Barthel, HJ Gores, G Schmeer, R Wachter - Physical and inorganic …, 1983 - Springer
In this paper a brief survey is given of the properties of non-aqueous electrolyte solutions
and their applications in chemistry and technology without going into the details of theory …

The decay of correlations in ionic fluids

RJF Leote de Carvalho, R Evans - Molecular Physics, 1994 - Taylor & Francis
The asymptotics of structural correlations in binary ionic fluids are investigated using an
extension of the pole analysis of the Ornstein-Zernike equation developed earlier for neutral …