Chalcogen-nitrogen chemistry involves the study of compounds that exhibit a linkage
between nitrogen and sulfur, selenium or tellurium atoms. Such studies have both …

Structures of molecules in the gas phase, determined experimentally, provide definitive
information about their identity, reactivity and other properties, free from intermolecular …

The first lanthanide complexes with a redox‐active sulfur diimide ligand,[LnCp* 2 (Me3SiN=)
2S](Ln= Sm, Eu, Yb; Cp*= η5‐C5Me5), are reported. The complexes were synthesized by …

This review highlights the most important advances in the heteroatom chemistry of 1, 3, 2, 4‐
benzodithiadiazines (π‐excessive and formally antiaromatic heterocycles), covering …

New chalcogen–nitrogen π-heterocycles covering 3, 1, 2, 4-benzothiaselenadiazines, 1, 3,
2, 4-benzodithiadiazines and 1, 2, 4, 3, 5-benzotrithiadiazepines were synthesized via the …

In contrast to thermolysis of 1, 3λ4δ2, 2, 4‐benzodithiadiazine (1) and its 5, 6, 7, 8‐tetrafluoro
derivative 2 in dilute (10–3 m) hydrocarbon solutions, which leads to persistent 1, 2, 3 …

Abstract Photolysis of 1, 3, 2, 4-benzodithiadiazine and its derivatives in hydrocarbon
solutions yields dinitrogen and stable 1, 2, 3-benzodithiazolyls (Herz radicals) whose …

The series of title compounds has been prepared through both electrophilic (C6HnF5− n−
N= S= N− SiMe3+ SCl2) and nucleophilic (C6HF4− S− N= S= N− SiMe3+ CsF) …

Mismatched molecular 1: 1 complexes were prepared from C10F8 and sulfur diimides Ar
N S N Ar 1 and Ar N S N–SiMe32, 3 (1, 2: Ar= 2, 6–dimethylphenyl; 3: Ar= phenyl) …

5, 6, 7, 8-Tetrafluoro-3λ4δ2, 1, 2, 4-benzothiaselenadiazine (1) is prepared by the
intramolecular nucleophilic cyclization of C6F5SeN S NSiMe3 (2) mediated by CsF …