Single‐atom catalysis in organic synthesis

VB Saptal, V Ruta, MA Bajada… - Angewandte Chemie …, 2023 - Wiley Online Library
Single‐atom catalysts hold the potential to significantly impact the chemical sector, pushing
the boundaries of catalysis in new, uncharted directions. These materials, featuring isolated …

Metal catalysts for heterogeneous catalysis: from single atoms to nanoclusters and nanoparticles

L Liu, A Corma - Chemical reviews, 2018 - ACS Publications
Metal species with different size (single atoms, nanoclusters, and nanoparticles) show
different catalytic behavior for various heterogeneous catalytic reactions. It has been shown …

Platinum-group-metal high-entropy-alloy nanoparticles

D Wu, K Kusada, T Yamamoto, T Toriyama… - Journal of the …, 2020 - ACS Publications
The platinum-group metals (PGMs) are six neighboring elements in the periodic table of the
elements. Each PGM can efficiently promote unique reactions, and therefore, alloying PGMs …

Opportunities for Electrocatalytic CO2 Reduction Enabled by Surface Ligands

Q Zhu, CJ Murphy, LR Baker - Journal of the American Chemical …, 2022 - ACS Publications
To achieve high selectivity in enzyme catalysis, nature carefully controls both the catalyst
active site and the pocket or environment that mediates access and the geometry of a …

New horizon of nanoparticle and cluster catalysis with dendrimers

K Yamamoto, T Imaoka, M Tanabe, T Kambe - Chemical reviews, 2019 - ACS Publications
Among various approaches synthesizing metal nanoparticles and tiny clusters, a template
method using dendrimers has significant advantages over other chemical approaches with …

Size and shape control of metal nanoparticles for reaction selectivity in catalysis

K An, GA Somorjai - ChemCatChem, 2012 - Wiley Online Library
A nanoparticle with well‐defined surfaces, prepared through colloidal chemistry, enables it
to be studied as a model heterogeneous catalyst. The colloidal synthetic approach provides …

Heterogeneous iridium single-atom molecular-like catalysis for epoxidation of ethylene

H Yang, X Wang, Q Liu, A Huang, X Zhang… - Journal of the …, 2023 - ACS Publications
Developing efficient and simple catalysts to reveal the key scientific issues in the
epoxidation of ethylene has been a long-standing goal for chemists, whereas a …

Nanostructured catalysts for organic transformations

LL Chng, N Erathodiyil, JY Ying - Accounts of chemical research, 2013 - ACS Publications
The development of green, sustainable and economical chemical processes is one of the
major challenges in chemistry. Besides the traditional need for efficient and selective …

A comparison of photocatalytic activities of gold nanoparticles following plasmonic and interband excitation and a strategy for harnessing interband hot carriers for …

J Zhao, SC Nguyen, R Ye, B Ye, H Weller… - ACS central …, 2017 - ACS Publications
Light driven excitation of gold nanoparticles (GNPs) has emerged as a potential strategy to
generate hot carriers for photocatalysis through excitation of localized surface plasmon …

Porous organic polymers containing active metal centers as catalysts for synthetic organic chemistry

S Kramer, NR Bennedsen, S Kegnæs - ACS Catalysis, 2018 - ACS Publications
Porous organic polymers (POPs) containing catalytically active mononuclear metal centers
can bridge the gap between homogeneous and heterogeneous catalysis. These materials …