Although known for over 90 years, only in the past two decades has the chemistry of diboron
(4) compounds been extensively explored. Many interesting structural features and reaction …

Alcohols, in particular polyols, are well-known for the synthesis of metal nanoparticles, often
acting as reducing agents, solvents, and stabilizers. Given not only their structural flexibility …

The conventional methods for preparing alkyl boronates often necessitate anhydrous and
demanding reaction conditions. Herein, a new, operationally simple decarboxylative …

This review describes the recent developments in the field of Suzuki–Miyaura cross‐
coupling reaction, in particular with regard to ligand‐free catalysis. The catalysts outlined …

This review describes the recent advancement of transition metal-catalyzed aromatic carbon-
boron bond construction processes. The efficacy of palladium, nickel and copper catalysis …

An efficient transition-metal free C–C bond cleavage/borylation of cycloketone oxime esters
has been described. In this reaction, the B2 (OH) 4 reagent not only served as the boron …

The use of low-cost manganese (II) bromide (MnBr2) and tetramethylethylenediamine
(TMEDA) catalyzes the cross coupling of (bis) pinacolatodiboron with a wide range of alkyl …

The use of low-cost iron (III) acetoacetate (Fe (acac) 3) and tetramethylethylenediamine
(TMEDA) enables the direct cross-coupling of alkyl halides with bis (pinacolato) diboron …

Palladium catalyzed coupling reactions have emerged as a versatile, convenient, selective
and mild protocol that can usually be adapted in any synthetic scheme for important target …

Activation of B2pin2 with tBuLi facilitates the Fe-catalyzed borylation of alkyl, allyl, benzyl,
and aryl halides via the formation of Li [B2pin2 (tBu)](1). The reaction of 1 with a …