Ammonia as hydrogen carrier: Advances in ammonia decomposition catalysts for promising hydrogen production
S Sun, Q Jiang, D Zhao, T Cao, H Sha, C Zhang… - … and Sustainable Energy …, 2022 - Elsevier
On-site ammonia decomposition has been considered as a potential candidate to alleviate
the challenges of hydrogen storage and transportation by utilizing NH 3 (with a high …
the challenges of hydrogen storage and transportation by utilizing NH 3 (with a high …
Advances in materials and applications of inorganic electrides
Electrides are materials in which electrons serve as anions. Here, the concept of inorganic
electrides is extended in several respects: from ionic crystals to intermetallic compounds in …
electrides is extended in several respects: from ionic crystals to intermetallic compounds in …
Vacancy-enabled N2 activation for ammonia synthesis on an Ni-loaded catalyst
Ammonia (NH3) is pivotal to the fertilizer industry and one of the most commonly produced
chemicals. The direct use of atmospheric nitrogen (N2) had been challenging, owing to its …
chemicals. The direct use of atmospheric nitrogen (N2) had been challenging, owing to its …
Surface Single-Cluster Catalyst for N2-to-NH3 Thermal Conversion
The ammonia synthesis from N2 is of vital importance, with imitating biological nitrogen
fixation attracted much interest. Herein, we investigate the catalytic mechanisms of N2-to …
fixation attracted much interest. Herein, we investigate the catalytic mechanisms of N2-to …
Dehydrated UiO‐66(SH)2: The Zr−O Cluster and Its Photocatalytic Role Mimicking the Biological Nitrogen Fixation
This work reports the dehydrated Zr‐based MOF UiO‐66 (SH) 2 as a visible‐light‐driven
photocatalyst to mimic the biological N2 fixation process. The 15N2 and other control …
photocatalyst to mimic the biological N2 fixation process. The 15N2 and other control …
Titanium-based hydrides as heterogeneous catalysts for ammonia synthesis
Y Kobayashi, Y Tang, T Kageyama… - Journal of the …, 2017 - ACS Publications
The problem of activating N2 and its subsequent hydrogenation to form NH3 has been
approached from many directions. One of these approaches involves the use of transition …
approached from many directions. One of these approaches involves the use of transition …
Dissociative and associative concerted mechanism for ammonia synthesis over Co-based catalyst
The current catalytic reaction mechanism for ammonia synthesis relies on either dissociative
or associative routes, in which adsorbed N2 dissociates directly or is hydrogenated step-by …
or associative routes, in which adsorbed N2 dissociates directly or is hydrogenated step-by …
Computational Study of MoN2 Monolayer as Electrochemical Catalysts for Nitrogen Reduction
Metallic two-dimensional materials are emerging as promising catalysts for several
reactions. This work reports a computational study of molybdenum nitride (MoN2) nanosheet …
reactions. This work reports a computational study of molybdenum nitride (MoN2) nanosheet …
Multiple reaction pathway on alkaline earth imide supported catalysts for efficient ammonia synthesis
The tunability of reaction pathways is required for exploring efficient and low cost catalysts
for ammonia synthesis. There is an obstacle by the limitations arising from scaling relation …
for ammonia synthesis. There is an obstacle by the limitations arising from scaling relation …
Onset potentials for different reaction mechanisms of nitrogen activation to ammonia on transition metal nitride electro-catalysts
Y Abghoui, E Skúlason - Catalysis Today, 2017 - Elsevier
Recent theoretical calculations with DFT suggest that transition metal nitrides (TMNs) are
promising materials to catalyze N 2 electroreduction to ammonia at ambient conditions. To …
promising materials to catalyze N 2 electroreduction to ammonia at ambient conditions. To …