In industries and academic laboratories, several late transition metal-catalyzed prerequisite
reactions are widely performed during single and multistep synthesis. However, besides the …

The preparation of primary amines attracts huge attention in the molecular synthetic
community. Indeed, amines play a crucial role in chemistry as they are important …

A terminal [Ni–OH] complex 1, supported by triflamide-functionalized NHC ligands, catalyzes
the hydrosilylative reduction of a range of primary amides into primary amines in good to …

This contribution described the chemoselective reduction of secondary carboxamides to
aldimines. To perform such challenging transformation, we reported a catalyzed …

Deoxygenative reduction of amides is considered as an attractive method for preparation of
synthetically valuable amines. However, the low electrophilicity of the amide carbonyl group …

We herein describe an efficient, CO2-tuned and highly selective C–O bond cleavage of N-
methylated formanilides. With easy-to-handle and commercially available NaBH4 as the …

Reported herein is a well-defined geometry-constrained tridentate NNN-cobalt complex for
the hydrosilylative reduction of secondary amides with the low-cost PMHS as the hydride …

A series of imino-POCNR, amino-POCNR2, and bis (phosphinite) POCOP pincer complexes
of Ni (II) were prepared and tested in catalytic deoxygenative hydroboration of amides with …

We demonstrate that using palladium acetate as a catalyst for reduction of DMF and isatin
derivatives by hydrosilanes, a cascade hydrosilylation and amino‐methylation reaction can …

A convenient procedure for the chemoselective reduction of tertiary amides at room
temperature in the presence of air and moisture using 1, 3-diphenyldisiloxane (DPDS) is …