Catalytic cross-coupling reactions have had a profound impact on the synthesis of
pharmaceuticals, biologically active natural products, and materials. 1 Such reactions …

The addition of an allylic organometallic compound to a carbonyl compound or an imine is of
great synthetic interest because in this reaction together with a new functionality (hydroxyl or …

Chiral BINOL-derived diols catalyze the enantioselective asymmetric allylboration of acyl
imines. The reaction requires 15 mol%(S)-3, 3 '-Ph2-BINOL as the catalyst and …

In this paper, indium (III) chloride was found to be a highly effective catalyst for the three-
component coupling reactions of aldehydes, alkynes, and amines (A3-coupling) via C− H …

Protected homoallylic amines are synthesized by the decarboxylative coupling of α-amino
acid derivatives. The catalytic C− C bond-forming reaction relies on the bioinspired …

A catalytic method for enantioselective synthesis of homoallylamides through Cu-catalyzed
reactions of stable and easily accessible (pinacolato) allylborons with aryl-, heteroaryl-, alkyl …

In the presence of a Cu (I)/NHC catalyst, the reactions of allylboronic pinacol esters with
CO2 (1 atm) are highly regioselective, giving exclusively the more substituted β, γ …

This review deals with organic reactions which are promoted by indium metal or indium
salts, with a focus on recent advances in stoichiometric and catalytic pathways. Applications …

We report a one-step catalytic, enantioselective method for the preparation of homoallylic N-
Boc amines directly from acetals. Reactive iminium ion intermediates are generated in situ …

Pyrazolo [3, 4-b] pyridine derivatives have been synthesized via one-pot condensation of 3-
methyl-1-phenyl-1H-pyrazolo-5-amine (1), formaldehyde (as paraformaldehyde)(2) and β …