Tetravalent Cerium Alkyl and Benzyl Complexes
High-valent cerium complexes of alkyl and benzyl ligands are unprecedented due to the
incompatibility of the typically highly oxidizing Ce4+ ion and the reducing alkyl or benzyl …
incompatibility of the typically highly oxidizing Ce4+ ion and the reducing alkyl or benzyl …
Facile Oxidation of Ce (III) to Ce (IV) Using Cu (I) Salts
AJ Gremillion, J Ross, X Yu, P Ishtaweera… - Inorganic …, 2024 - ACS Publications
The synthesis, luminescence, and electrochemical properties of the Ce (III)
compound,[(C5Me5) 2 (2, 6-iPr2C6H3O) Ce (THF)], 1, were investigated. Based on the …
compound,[(C5Me5) 2 (2, 6-iPr2C6H3O) Ce (THF)], 1, were investigated. Based on the …
Organolanthanide Complexes Containing Ln–CH3 σ-bonds: Unexpectedly Similar Hydrolysis Rates for Trivalent and Tetravalent Organocerium
Z Shafi, JK Gibson - Inorganic Chemistry, 2023 - ACS Publications
We report the gas-phase preparation, isolation, and reactivity of a series of
organolanthanides featuring the Ln–CH3 bond. The complexes are formed by …
organolanthanides featuring the Ln–CH3 bond. The complexes are formed by …
Synthesis and reactivity of a uranium (iv) complex supported by a monoanionic nitrogen–phosphorus ligand
K Li, J He, Y Zhao, C Zhu - Inorganic Chemistry Frontiers, 2023 - pubs.rsc.org
A monoanionic nitrogen–phosphorus ligand (CH3) 2NCH2CH2NHPiPr2 (L3) was designed
and the corresponding U (IV) chloride complex {[(CH3) 2NCH2CH2NPiPr2] 2UCl2}(1) and U …
and the corresponding U (IV) chloride complex {[(CH3) 2NCH2CH2NPiPr2] 2UCl2}(1) and U …
Realization of Organocerium-Based Fullerene Molecular Materials Showing Mott Insulator-Type Behavior
Electron-rich organocerium complexes (C5Me4H) 3Ce and [(C5Me5) 2Ce (ortho-oxa)], with
redox potentials E 1/2=− 0.82 V and E 1/2=− 0.86 V versus Fc/Fc+, respectively, were …
redox potentials E 1/2=− 0.82 V and E 1/2=− 0.86 V versus Fc/Fc+, respectively, were …
Cerium (iii) yldiide complexes with divergent CO reactivity
AJ Gremillion, H Kumar, I Del Rosal… - Chemical …, 2025 - pubs.rsc.org
Synthesis of cerium yldiide complexes and their reactivity with CO is demonstrated. In the
case of the sulphur-tethered yldiide, the ketenyl complex is formed with release of PPh3 …
case of the sulphur-tethered yldiide, the ketenyl complex is formed with release of PPh3 …